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Spectroscopic X-ray and Mössbauer Characterization of M(6) and M(5) Iron(Molybdenum)-Carbonyl Carbide Clusters: High Carbide-Iron Covalency Enhances Local Iron Site Electron Density Despite Cluster Oxidation

[Image: see text] The present study employs a suite of spectroscopic techniques to evaluate the electronic and bonding characteristics of the interstitial carbide in a set of iron-carbonyl-carbide clusters, one of which is substituted with a molybdenum atom. The M(6)C and M(5)C clusters are the dian...

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Detalles Bibliográficos
Autores principales:	McGale, Jeremy, Cutsail, George E., Joseph, Chris, Rose, Michael J., DeBeer, Serena
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2019
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6784818/ https://www.ncbi.nlm.nih.gov/pubmed/31553598 http://dx.doi.org/10.1021/acs.inorgchem.9b01870

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