A Guanidine-Based Superbase as Efficient Chemiluminescence Booster

We introduce the guanidine-based superbase 1,5,7-triaza-bicyclo-[4.4.0]dec-5-ene (TBD) as efficient enabler for chemiluminescence (CL) based on luminol in a simple, ready-to-use two component system. The strong CL is generated by the superbase’s properties as peroxidase mimetic and bifunctional core...

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Detalles Bibliográficos
Autores principales: Geiselhart, Christina M., Schmitt, Christian W., Jöckle, Philipp, Mutlu, Hatice, Barner-Kowollik, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6786995/
https://www.ncbi.nlm.nih.gov/pubmed/31601903
http://dx.doi.org/10.1038/s41598-019-51105-z
Descripción
Sumario:We introduce the guanidine-based superbase 1,5,7-triaza-bicyclo-[4.4.0]dec-5-ene (TBD) as efficient enabler for chemiluminescence (CL) based on luminol in a simple, ready-to-use two component system. The strong CL is generated by the superbase’s properties as peroxidase mimetic and bifunctional coreactant. The herein established concept allows for CL enabling molecules (superbases) to be readily implemented in larger molecular structures, including in polymers.

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