A Guanidine-Based Superbase as Efficient Chemiluminescence Booster

We introduce the guanidine-based superbase 1,5,7-triaza-bicyclo-[4.4.0]dec-5-ene (TBD) as efficient enabler for chemiluminescence (CL) based on luminol in a simple, ready-to-use two component system. The strong CL is generated by the superbase’s properties as peroxidase mimetic and bifunctional core...

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Autores principales: Geiselhart, Christina M., Schmitt, Christian W., Jöckle, Philipp, Mutlu, Hatice, Barner-Kowollik, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6786995/
https://www.ncbi.nlm.nih.gov/pubmed/31601903
http://dx.doi.org/10.1038/s41598-019-51105-z
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author Geiselhart, Christina M.
Schmitt, Christian W.
Jöckle, Philipp
Mutlu, Hatice
Barner-Kowollik, Christopher
author_facet Geiselhart, Christina M.
Schmitt, Christian W.
Jöckle, Philipp
Mutlu, Hatice
Barner-Kowollik, Christopher
author_sort Geiselhart, Christina M.
collection PubMed
description We introduce the guanidine-based superbase 1,5,7-triaza-bicyclo-[4.4.0]dec-5-ene (TBD) as efficient enabler for chemiluminescence (CL) based on luminol in a simple, ready-to-use two component system. The strong CL is generated by the superbase’s properties as peroxidase mimetic and bifunctional coreactant. The herein established concept allows for CL enabling molecules (superbases) to be readily implemented in larger molecular structures, including in polymers.
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spelling pubmed-67869952019-10-17 A Guanidine-Based Superbase as Efficient Chemiluminescence Booster Geiselhart, Christina M. Schmitt, Christian W. Jöckle, Philipp Mutlu, Hatice Barner-Kowollik, Christopher Sci Rep Article We introduce the guanidine-based superbase 1,5,7-triaza-bicyclo-[4.4.0]dec-5-ene (TBD) as efficient enabler for chemiluminescence (CL) based on luminol in a simple, ready-to-use two component system. The strong CL is generated by the superbase’s properties as peroxidase mimetic and bifunctional coreactant. The herein established concept allows for CL enabling molecules (superbases) to be readily implemented in larger molecular structures, including in polymers. Nature Publishing Group UK 2019-10-10 /pmc/articles/PMC6786995/ /pubmed/31601903 http://dx.doi.org/10.1038/s41598-019-51105-z Text en © The Author(s) 2019 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Geiselhart, Christina M.
Schmitt, Christian W.
Jöckle, Philipp
Mutlu, Hatice
Barner-Kowollik, Christopher
A Guanidine-Based Superbase as Efficient Chemiluminescence Booster
title A Guanidine-Based Superbase as Efficient Chemiluminescence Booster
title_full A Guanidine-Based Superbase as Efficient Chemiluminescence Booster
title_fullStr A Guanidine-Based Superbase as Efficient Chemiluminescence Booster
title_full_unstemmed A Guanidine-Based Superbase as Efficient Chemiluminescence Booster
title_short A Guanidine-Based Superbase as Efficient Chemiluminescence Booster
title_sort guanidine-based superbase as efficient chemiluminescence booster
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6786995/
https://www.ncbi.nlm.nih.gov/pubmed/31601903
http://dx.doi.org/10.1038/s41598-019-51105-z
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