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Homocubane Chemistry: Synthesis and Structures of Mono- and Dicobaltaheteroborane Analogues of Tris- and Tetrahomocubanes
[Image: see text] Room-temperature reactions between [Cp*CoCl](2) (Cp* = η(5)-C(5)Me(5)) and large excess of [BH(2)E(3)]Li (E = S or Se) led to the formation of homocubane derivatives, 1–7. These species are bimetallic tetrahomocubane, [(Cp*Co)(2)(μ-S)(4)(μ(3)-S)(4)B(2)H(2)], 1; bimetallic trishomoc...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6788070/ https://www.ncbi.nlm.nih.gov/pubmed/31616847 http://dx.doi.org/10.1021/acsomega.9b02568 |