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Subcomponent Self‐Assembly of a Cyclic Tetranuclear Fe(II) Helicate in a Highly Diastereoselective Self‐Sorting Manner
An enantiomerically pure diamine based on the 4,15‐difunctionalized [2.2]paracyclophane scaffold and 2‐formylpyridine self‐assemble into an optically pure cyclic metallosupramolecular Fe(4)L(6) helicate upon mixing with iron(II) ions in a diastereoselective subcomponent self‐assembly process. The cy...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6790559/ https://www.ncbi.nlm.nih.gov/pubmed/31314931 http://dx.doi.org/10.1002/chem.201903164 |