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Subcomponent Self‐Assembly of a Cyclic Tetranuclear Fe(II) Helicate in a Highly Diastereoselective Self‐Sorting Manner

An enantiomerically pure diamine based on the 4,15‐difunctionalized [2.2]paracyclophane scaffold and 2‐formylpyridine self‐assemble into an optically pure cyclic metallosupramolecular Fe(4)L(6) helicate upon mixing with iron(II) ions in a diastereoselective subcomponent self‐assembly process. The cy...

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Detalles Bibliográficos
Autores principales: Anhäuser, Jana, Puttreddy, Rakesh, Glanz, Lukas, Schneider, Andreas, Engeser, Marianne, Rissanen, Kari, Lützen, Arne
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6790559/
https://www.ncbi.nlm.nih.gov/pubmed/31314931
http://dx.doi.org/10.1002/chem.201903164