Why Do Five Ga(+) Cations Form a Ligand‐Stabilized [Ga(5)](5+) Pentagon and How Does a 5:1 Salt Pack in the Solid State?

The reaction of the Ga(+) source [Ga(PhF)(2)](+)[Al(OR(F))(4)](−) with the neutral σ‐donor ligand dmap (4‐Me(2)N‐C(6)H(4)N) produces the unexpectedly large and fivefold positively charged cluster cation salt [Ga(5)(dmap)(10)](5+)([Al(OR(F))(4)](−))(5). It includes a regular and planar Ga(5) pentagon...

Descripción completa

Detalles Bibliográficos
Autores principales: Glootz, Kim, Himmel, Daniel, Kratzert, Daniel, Butschke, Burkhard, Scherer, Harald, Krossing, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6790617/
https://www.ncbi.nlm.nih.gov/pubmed/31369694
http://dx.doi.org/10.1002/anie.201907974

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6790617/
https://www.ncbi.nlm.nih.gov/pubmed/31369694
http://dx.doi.org/10.1002/anie.201907974

Ejemplares similares