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Why Do Five Ga(+) Cations Form a Ligand‐Stabilized [Ga(5)](5+) Pentagon and How Does a 5:1 Salt Pack in the Solid State?
The reaction of the Ga(+) source [Ga(PhF)(2)](+)[Al(OR(F))(4)](−) with the neutral σ‐donor ligand dmap (4‐Me(2)N‐C(6)H(4)N) produces the unexpectedly large and fivefold positively charged cluster cation salt [Ga(5)(dmap)(10)](5+)([Al(OR(F))(4)](−))(5). It includes a regular and planar Ga(5) pentagon...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6790617/ https://www.ncbi.nlm.nih.gov/pubmed/31369694 http://dx.doi.org/10.1002/anie.201907974 |