BN‐ and BO‐Doped Inorganic–Organic Hybrid Polymers with Sulfoximine Core Units

While polysulfones constitute a class of well‐established, highly valuable applied materials, knowledge about polymers based on the related sulfoximine group is very limited. We have employed functionalized diaryl sulfoximines and a p‐phenylene bisborane as building blocks for unprecedented BN‐ and...

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Detalles Bibliográficos
Autores principales: Brosge, Felix, Lorenz, Thomas, Helten, Holger, Bolm, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6790941/
https://www.ncbi.nlm.nih.gov/pubmed/31433083
http://dx.doi.org/10.1002/chem.201903289
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author Brosge, Felix
Lorenz, Thomas
Helten, Holger
Bolm, Carsten
author_facet Brosge, Felix
Lorenz, Thomas
Helten, Holger
Bolm, Carsten
author_sort Brosge, Felix
collection PubMed
description While polysulfones constitute a class of well‐established, highly valuable applied materials, knowledge about polymers based on the related sulfoximine group is very limited. We have employed functionalized diaryl sulfoximines and a p‐phenylene bisborane as building blocks for unprecedented BN‐ and BO‐doped alternating inorganic–organic hybrid copolymers. While the former were accessed by a facile silicon/boron exchange protocol, the synthesis of polymers with main‐chain B–O linkages was achieved by salt elimination.
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spelling pubmed-67909412019-10-21 BN‐ and BO‐Doped Inorganic–Organic Hybrid Polymers with Sulfoximine Core Units Brosge, Felix Lorenz, Thomas Helten, Holger Bolm, Carsten Chemistry Communications While polysulfones constitute a class of well‐established, highly valuable applied materials, knowledge about polymers based on the related sulfoximine group is very limited. We have employed functionalized diaryl sulfoximines and a p‐phenylene bisborane as building blocks for unprecedented BN‐ and BO‐doped alternating inorganic–organic hybrid copolymers. While the former were accessed by a facile silicon/boron exchange protocol, the synthesis of polymers with main‐chain B–O linkages was achieved by salt elimination. John Wiley and Sons Inc. 2019-09-09 2019-10-01 /pmc/articles/PMC6790941/ /pubmed/31433083 http://dx.doi.org/10.1002/chem.201903289 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Brosge, Felix
Lorenz, Thomas
Helten, Holger
Bolm, Carsten
BN‐ and BO‐Doped Inorganic–Organic Hybrid Polymers with Sulfoximine Core Units
title BN‐ and BO‐Doped Inorganic–Organic Hybrid Polymers with Sulfoximine Core Units
title_full BN‐ and BO‐Doped Inorganic–Organic Hybrid Polymers with Sulfoximine Core Units
title_fullStr BN‐ and BO‐Doped Inorganic–Organic Hybrid Polymers with Sulfoximine Core Units
title_full_unstemmed BN‐ and BO‐Doped Inorganic–Organic Hybrid Polymers with Sulfoximine Core Units
title_short BN‐ and BO‐Doped Inorganic–Organic Hybrid Polymers with Sulfoximine Core Units
title_sort bn‐ and bo‐doped inorganic–organic hybrid polymers with sulfoximine core units
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6790941/
https://www.ncbi.nlm.nih.gov/pubmed/31433083
http://dx.doi.org/10.1002/chem.201903289
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