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The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs
Cycloparaphenylenes (CPPs) and their analogs have recently attracted much attention due to their aesthetical structures and optoelectronic properties with radial π-conjugation systems. The past 10 years have witnessed a remarkable advancement in CPPs research, from synthetic methodology to optoelect...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6794338/ https://www.ncbi.nlm.nih.gov/pubmed/31649920 http://dx.doi.org/10.3389/fchem.2019.00668 |
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author | Lu, Dapeng Huang, Qiang Wang, Shengda Wang, Jinyi Huang, Pingsen Du, Pingwu |
author_facet | Lu, Dapeng Huang, Qiang Wang, Shengda Wang, Jinyi Huang, Pingsen Du, Pingwu |
author_sort | Lu, Dapeng |
collection | PubMed |
description | Cycloparaphenylenes (CPPs) and their analogs have recently attracted much attention due to their aesthetical structures and optoelectronic properties with radial π-conjugation systems. The past 10 years have witnessed a remarkable advancement in CPPs research, from synthetic methodology to optoelectronic investigations. In this present minireview, we highlight the supramolecular chemistry of CPPs and their analogs, mainly focusing on the size-selective encapsulation of fullerenes, endohedral metallofullerenes, and small molecules by these hoop-shaped macrocycles. We will also discuss the assembly of molecular bearings using some belt-persistent tubular cycloarylene molecules and fullerenes, photoinduced electron transfer properties in supramolecular systems containing carbon nanohoop hosts and fullerene guests, as well as the shape recognition properties for structure self-sorting by using dumbbell-shaped dimer of [60]fullerene ligand. Besides, the supramolecular complexes with guest molecules other than fullerenes, such as CPPs themselves, iodine, pyridinium cations, and bowl-shaped corannulene, are also discussed. |
format | Online Article Text |
id | pubmed-6794338 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | Frontiers Media S.A. |
record_format | MEDLINE/PubMed |
spelling | pubmed-67943382019-10-24 The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs Lu, Dapeng Huang, Qiang Wang, Shengda Wang, Jinyi Huang, Pingsen Du, Pingwu Front Chem Chemistry Cycloparaphenylenes (CPPs) and their analogs have recently attracted much attention due to their aesthetical structures and optoelectronic properties with radial π-conjugation systems. The past 10 years have witnessed a remarkable advancement in CPPs research, from synthetic methodology to optoelectronic investigations. In this present minireview, we highlight the supramolecular chemistry of CPPs and their analogs, mainly focusing on the size-selective encapsulation of fullerenes, endohedral metallofullerenes, and small molecules by these hoop-shaped macrocycles. We will also discuss the assembly of molecular bearings using some belt-persistent tubular cycloarylene molecules and fullerenes, photoinduced electron transfer properties in supramolecular systems containing carbon nanohoop hosts and fullerene guests, as well as the shape recognition properties for structure self-sorting by using dumbbell-shaped dimer of [60]fullerene ligand. Besides, the supramolecular complexes with guest molecules other than fullerenes, such as CPPs themselves, iodine, pyridinium cations, and bowl-shaped corannulene, are also discussed. Frontiers Media S.A. 2019-10-09 /pmc/articles/PMC6794338/ /pubmed/31649920 http://dx.doi.org/10.3389/fchem.2019.00668 Text en Copyright © 2019 Lu, Huang, Wang, Wang, Huang and Du. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms. |
spellingShingle | Chemistry Lu, Dapeng Huang, Qiang Wang, Shengda Wang, Jinyi Huang, Pingsen Du, Pingwu The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs |
title | The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs |
title_full | The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs |
title_fullStr | The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs |
title_full_unstemmed | The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs |
title_short | The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs |
title_sort | supramolecular chemistry of cycloparaphenylenes and their analogs |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6794338/ https://www.ncbi.nlm.nih.gov/pubmed/31649920 http://dx.doi.org/10.3389/fchem.2019.00668 |
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