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N-Propyl-N-Methylpyrrolidinium Difluoro(oxalato)borate as a Novel Electrolyte for High-Voltage Supercapacitor
Development of high voltage electrolyte is one of the effective ways to improve the performance of supercapacitor. The new ionic liquid N-propyl-N-methylpyrrolidinium difluoro(oxalato)borate (Py(13)DFOB) was designed and mixed with propylene carbonate (PC) as electrolyte for supercapacitor. The oper...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6794414/ https://www.ncbi.nlm.nih.gov/pubmed/31649918 http://dx.doi.org/10.3389/fchem.2019.00664 |
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author | Zhang, Weili Zhang, Fuming Zhang, Peng Liang, Shuo Shi, Zhiqiang |
author_facet | Zhang, Weili Zhang, Fuming Zhang, Peng Liang, Shuo Shi, Zhiqiang |
author_sort | Zhang, Weili |
collection | PubMed |
description | Development of high voltage electrolyte is one of the effective ways to improve the performance of supercapacitor. The new ionic liquid N-propyl-N-methylpyrrolidinium difluoro(oxalato)borate (Py(13)DFOB) was designed and mixed with propylene carbonate (PC) as electrolyte for supercapacitor. The operating voltage of the new electrolyte system has been proven to be up to 3.0 V by a series of electrochemical techniques. Surprisingly, the new salt exhibits nearly symmetric capacitance contribution in the positive and negative electrodes, leading to a high capacitance value of 130 F g(−1). The energy and power density of EDLCs using Py(13)DFOB in the PC electrolyte reach 39.06 Wh kg(−1) (100 mA g(−1)) and 8.03 kW kg(−1) (5,000 mA g(−1)), respectively, at the working voltage of 3.0 V, significantly exceeding the performance of commercial electrolyte tetraethylammonium tetrafluoroborate (TEABF(4)). The results indicate that Py(13)DFOB can be a promising electrolyte salt for supercapacitor. |
format | Online Article Text |
id | pubmed-6794414 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | Frontiers Media S.A. |
record_format | MEDLINE/PubMed |
spelling | pubmed-67944142019-10-24 N-Propyl-N-Methylpyrrolidinium Difluoro(oxalato)borate as a Novel Electrolyte for High-Voltage Supercapacitor Zhang, Weili Zhang, Fuming Zhang, Peng Liang, Shuo Shi, Zhiqiang Front Chem Chemistry Development of high voltage electrolyte is one of the effective ways to improve the performance of supercapacitor. The new ionic liquid N-propyl-N-methylpyrrolidinium difluoro(oxalato)borate (Py(13)DFOB) was designed and mixed with propylene carbonate (PC) as electrolyte for supercapacitor. The operating voltage of the new electrolyte system has been proven to be up to 3.0 V by a series of electrochemical techniques. Surprisingly, the new salt exhibits nearly symmetric capacitance contribution in the positive and negative electrodes, leading to a high capacitance value of 130 F g(−1). The energy and power density of EDLCs using Py(13)DFOB in the PC electrolyte reach 39.06 Wh kg(−1) (100 mA g(−1)) and 8.03 kW kg(−1) (5,000 mA g(−1)), respectively, at the working voltage of 3.0 V, significantly exceeding the performance of commercial electrolyte tetraethylammonium tetrafluoroborate (TEABF(4)). The results indicate that Py(13)DFOB can be a promising electrolyte salt for supercapacitor. Frontiers Media S.A. 2019-10-09 /pmc/articles/PMC6794414/ /pubmed/31649918 http://dx.doi.org/10.3389/fchem.2019.00664 Text en Copyright © 2019 Zhang, Zhang, Zhang, Liang and Shi. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms. |
spellingShingle | Chemistry Zhang, Weili Zhang, Fuming Zhang, Peng Liang, Shuo Shi, Zhiqiang N-Propyl-N-Methylpyrrolidinium Difluoro(oxalato)borate as a Novel Electrolyte for High-Voltage Supercapacitor |
title | N-Propyl-N-Methylpyrrolidinium Difluoro(oxalato)borate as a Novel Electrolyte for High-Voltage Supercapacitor |
title_full | N-Propyl-N-Methylpyrrolidinium Difluoro(oxalato)borate as a Novel Electrolyte for High-Voltage Supercapacitor |
title_fullStr | N-Propyl-N-Methylpyrrolidinium Difluoro(oxalato)borate as a Novel Electrolyte for High-Voltage Supercapacitor |
title_full_unstemmed | N-Propyl-N-Methylpyrrolidinium Difluoro(oxalato)borate as a Novel Electrolyte for High-Voltage Supercapacitor |
title_short | N-Propyl-N-Methylpyrrolidinium Difluoro(oxalato)borate as a Novel Electrolyte for High-Voltage Supercapacitor |
title_sort | n-propyl-n-methylpyrrolidinium difluoro(oxalato)borate as a novel electrolyte for high-voltage supercapacitor |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6794414/ https://www.ncbi.nlm.nih.gov/pubmed/31649918 http://dx.doi.org/10.3389/fchem.2019.00664 |
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