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Probing ultrafast C–Br bond fission in the UV photochemistry of bromoform with core-to-valence transient absorption spectroscopy
UV pump–extreme UV (XUV) probe femtosecond transient absorption spectroscopy is used to study the 268 nm induced photodissociation dynamics of bromoform (CHBr(3)). Core-to-valence transitions at the Br(3d) absorption edge (∼70 eV) provide an atomic scale perspective of the reaction, sensitive to cha...
Autores principales: | Toulson, Benjamin W., Borgwardt, Mario, Wang, Han, Lackner, Florian, Chatterley, Adam S., Pemmaraju, C. D., Neumark, Daniel M., Leone, Stephen R., Prendergast, David, Gessner, Oliver |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Crystallographic Association
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6800284/ https://www.ncbi.nlm.nih.gov/pubmed/31649963 http://dx.doi.org/10.1063/1.5113798 |
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