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C(60) ions of 1 MeV are slow but elongate nanoparticles like swift heavy ions of hundreds MeV

This study reports that high fluence fullerene ion (C(60)(+)) irradiation of 1–6 MeV, which was made possible by a new-type of high-flux ion source, elongates metal nanoparticles (NPs) in amorphous SiO(2) as efficiently as swift heavy ions (SHIs) of 200 MeV Xe(14+), i.e., two orders of the magnitude...

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Autores principales: Amekura, H., Narumi, K., Chiba, A., Hirano, Y., Yamada, K., Tsuya, D., Yamamoto, S., Okubo, N., Ishikawa, N., Saitoh, Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6800440/
https://www.ncbi.nlm.nih.gov/pubmed/31628343
http://dx.doi.org/10.1038/s41598-019-49645-5
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author Amekura, H.
Narumi, K.
Chiba, A.
Hirano, Y.
Yamada, K.
Tsuya, D.
Yamamoto, S.
Okubo, N.
Ishikawa, N.
Saitoh, Y.
author_facet Amekura, H.
Narumi, K.
Chiba, A.
Hirano, Y.
Yamada, K.
Tsuya, D.
Yamamoto, S.
Okubo, N.
Ishikawa, N.
Saitoh, Y.
author_sort Amekura, H.
collection PubMed
description This study reports that high fluence fullerene ion (C(60)(+)) irradiation of 1–6 MeV, which was made possible by a new-type of high-flux ion source, elongates metal nanoparticles (NPs) in amorphous SiO(2) as efficiently as swift heavy ions (SHIs) of 200 MeV Xe(14+), i.e., two orders of the magnitude higher energy ions. Comparing the irradiation effects induced by both the beams, the stopping processes of C(60) ions in SiO(2) are discussed in this paper. Despite of having almost the same elongation efficiency, the C(60)(+) irradiation induced ~10 times more efficient sputtering due to the clustering enhancement and/or the synergy effect. Ion tracks of ~10.4 nm in diameter and 60–80 nm in length were observed in crystalline SiO(2) under 4 MeV C(60) irradiation(.) While the track diameter was comparable to those by SHIs of the same electronic stopping, much shorter track lengths than those predicted by a rigid C(60) molecule model indicates that the fragmentation occurred due to nuclear collisions. The elongation of the metal NPs was induced only down to the depth where the tracks were observed but not beyond.
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spelling pubmed-68004402019-10-25 C(60) ions of 1 MeV are slow but elongate nanoparticles like swift heavy ions of hundreds MeV Amekura, H. Narumi, K. Chiba, A. Hirano, Y. Yamada, K. Tsuya, D. Yamamoto, S. Okubo, N. Ishikawa, N. Saitoh, Y. Sci Rep Article This study reports that high fluence fullerene ion (C(60)(+)) irradiation of 1–6 MeV, which was made possible by a new-type of high-flux ion source, elongates metal nanoparticles (NPs) in amorphous SiO(2) as efficiently as swift heavy ions (SHIs) of 200 MeV Xe(14+), i.e., two orders of the magnitude higher energy ions. Comparing the irradiation effects induced by both the beams, the stopping processes of C(60) ions in SiO(2) are discussed in this paper. Despite of having almost the same elongation efficiency, the C(60)(+) irradiation induced ~10 times more efficient sputtering due to the clustering enhancement and/or the synergy effect. Ion tracks of ~10.4 nm in diameter and 60–80 nm in length were observed in crystalline SiO(2) under 4 MeV C(60) irradiation(.) While the track diameter was comparable to those by SHIs of the same electronic stopping, much shorter track lengths than those predicted by a rigid C(60) molecule model indicates that the fragmentation occurred due to nuclear collisions. The elongation of the metal NPs was induced only down to the depth where the tracks were observed but not beyond. Nature Publishing Group UK 2019-10-18 /pmc/articles/PMC6800440/ /pubmed/31628343 http://dx.doi.org/10.1038/s41598-019-49645-5 Text en © The Author(s) 2019 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Amekura, H.
Narumi, K.
Chiba, A.
Hirano, Y.
Yamada, K.
Tsuya, D.
Yamamoto, S.
Okubo, N.
Ishikawa, N.
Saitoh, Y.
C(60) ions of 1 MeV are slow but elongate nanoparticles like swift heavy ions of hundreds MeV
title C(60) ions of 1 MeV are slow but elongate nanoparticles like swift heavy ions of hundreds MeV
title_full C(60) ions of 1 MeV are slow but elongate nanoparticles like swift heavy ions of hundreds MeV
title_fullStr C(60) ions of 1 MeV are slow but elongate nanoparticles like swift heavy ions of hundreds MeV
title_full_unstemmed C(60) ions of 1 MeV are slow but elongate nanoparticles like swift heavy ions of hundreds MeV
title_short C(60) ions of 1 MeV are slow but elongate nanoparticles like swift heavy ions of hundreds MeV
title_sort c(60) ions of 1 mev are slow but elongate nanoparticles like swift heavy ions of hundreds mev
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6800440/
https://www.ncbi.nlm.nih.gov/pubmed/31628343
http://dx.doi.org/10.1038/s41598-019-49645-5
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