Substituted 1,3,5-Triazine Hexacarboxylates as Potential Linkers for MOFs

Hexacarboxylates are promising linkers for MOFs such as NU-109 or NU-110, which possess large values for surfaces and pore volumina. Starting from 2,4,6-tris(bromoaryl)-1,3,5-triazines, palladium-catalyzed cross coupling reactions (Suzuki-Miyaura, Sonogashira-Hagihara) form elongated hexacarboxylate...

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Autores principales: Klinkebiel, Arne, Beyer, Ole, Lüning, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6804050/
https://www.ncbi.nlm.nih.gov/pubmed/31557929
http://dx.doi.org/10.3390/molecules24193480
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author Klinkebiel, Arne
Beyer, Ole
Lüning, Ulrich
author_facet Klinkebiel, Arne
Beyer, Ole
Lüning, Ulrich
author_sort Klinkebiel, Arne
collection PubMed
description Hexacarboxylates are promising linkers for MOFs such as NU-109 or NU-110, which possess large values for surfaces and pore volumina. Starting from 2,4,6-tris(bromoaryl)-1,3,5-triazines, palladium-catalyzed cross coupling reactions (Suzuki-Miyaura, Sonogashira-Hagihara) form elongated hexacarboxylate linkers. Eight new 2,4,6-tris(biphenyl) and 2,4,6-tris(phenylethynylphenyl) 1,3,5-triazines have been prepared in quantities ranging from 40 mg to 1.1 g. In five cases, one of the arms of the linker carries an additional functionality (NO(2) or OMe).
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spelling pubmed-68040502019-11-18 Substituted 1,3,5-Triazine Hexacarboxylates as Potential Linkers for MOFs Klinkebiel, Arne Beyer, Ole Lüning, Ulrich Molecules Article Hexacarboxylates are promising linkers for MOFs such as NU-109 or NU-110, which possess large values for surfaces and pore volumina. Starting from 2,4,6-tris(bromoaryl)-1,3,5-triazines, palladium-catalyzed cross coupling reactions (Suzuki-Miyaura, Sonogashira-Hagihara) form elongated hexacarboxylate linkers. Eight new 2,4,6-tris(biphenyl) and 2,4,6-tris(phenylethynylphenyl) 1,3,5-triazines have been prepared in quantities ranging from 40 mg to 1.1 g. In five cases, one of the arms of the linker carries an additional functionality (NO(2) or OMe). MDPI 2019-09-25 /pmc/articles/PMC6804050/ /pubmed/31557929 http://dx.doi.org/10.3390/molecules24193480 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Klinkebiel, Arne
Beyer, Ole
Lüning, Ulrich
Substituted 1,3,5-Triazine Hexacarboxylates as Potential Linkers for MOFs
title Substituted 1,3,5-Triazine Hexacarboxylates as Potential Linkers for MOFs
title_full Substituted 1,3,5-Triazine Hexacarboxylates as Potential Linkers for MOFs
title_fullStr Substituted 1,3,5-Triazine Hexacarboxylates as Potential Linkers for MOFs
title_full_unstemmed Substituted 1,3,5-Triazine Hexacarboxylates as Potential Linkers for MOFs
title_short Substituted 1,3,5-Triazine Hexacarboxylates as Potential Linkers for MOFs
title_sort substituted 1,3,5-triazine hexacarboxylates as potential linkers for mofs
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6804050/
https://www.ncbi.nlm.nih.gov/pubmed/31557929
http://dx.doi.org/10.3390/molecules24193480
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