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Application of Core–Shell Metallic Nanoparticles in Hybridized Perovskite Solar Cell—Various Channels of Plasmon Photovoltaic Effect
We analyze the microscopic mechanism of the improvement of solar cell efficiency by plasmons in metallic components embedded in active optical medium of a cell. We focus on the explanation of the observed new channel of plasmon photovoltaic effect related to the influence of plasmons onto the intern...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6804171/ https://www.ncbi.nlm.nih.gov/pubmed/31569454 http://dx.doi.org/10.3390/ma12193192 |
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author | Kluczyk-Korch, Katarzyna David, Christin Jacak, Witold Jacak, Janusz |
author_facet | Kluczyk-Korch, Katarzyna David, Christin Jacak, Witold Jacak, Janusz |
author_sort | Kluczyk-Korch, Katarzyna |
collection | PubMed |
description | We analyze the microscopic mechanism of the improvement of solar cell efficiency by plasmons in metallic components embedded in active optical medium of a cell. We focus on the explanation of the observed new channel of plasmon photovoltaic effect related to the influence of plasmons onto the internal cell electricity beyond the previously known plasmon mediated absorption of photons. The model situation we analyze is the hybrid chemical perovskite solar cell CH [Formula: see text] NH [Formula: see text] PbI [Formula: see text] Cl [Formula: see text] with inclusion of core–shell Au/Si0 [Formula: see text] nanoparticles filling pores in the Al [Formula: see text] O [Formula: see text] or TiO [Formula: see text] porous bases at the bottom of perovskite layer, application of which improved the cell efficiency from 10.7 to 11.4% and from 8.4 to 9.5%, respectively, as demonstrated experimentally, mostly due to the reduction by plasmons of the exciton binding energy. |
format | Online Article Text |
id | pubmed-6804171 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-68041712019-11-18 Application of Core–Shell Metallic Nanoparticles in Hybridized Perovskite Solar Cell—Various Channels of Plasmon Photovoltaic Effect Kluczyk-Korch, Katarzyna David, Christin Jacak, Witold Jacak, Janusz Materials (Basel) Article We analyze the microscopic mechanism of the improvement of solar cell efficiency by plasmons in metallic components embedded in active optical medium of a cell. We focus on the explanation of the observed new channel of plasmon photovoltaic effect related to the influence of plasmons onto the internal cell electricity beyond the previously known plasmon mediated absorption of photons. The model situation we analyze is the hybrid chemical perovskite solar cell CH [Formula: see text] NH [Formula: see text] PbI [Formula: see text] Cl [Formula: see text] with inclusion of core–shell Au/Si0 [Formula: see text] nanoparticles filling pores in the Al [Formula: see text] O [Formula: see text] or TiO [Formula: see text] porous bases at the bottom of perovskite layer, application of which improved the cell efficiency from 10.7 to 11.4% and from 8.4 to 9.5%, respectively, as demonstrated experimentally, mostly due to the reduction by plasmons of the exciton binding energy. MDPI 2019-09-29 /pmc/articles/PMC6804171/ /pubmed/31569454 http://dx.doi.org/10.3390/ma12193192 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Kluczyk-Korch, Katarzyna David, Christin Jacak, Witold Jacak, Janusz Application of Core–Shell Metallic Nanoparticles in Hybridized Perovskite Solar Cell—Various Channels of Plasmon Photovoltaic Effect |
title | Application of Core–Shell Metallic Nanoparticles in Hybridized Perovskite Solar Cell—Various Channels of Plasmon Photovoltaic Effect |
title_full | Application of Core–Shell Metallic Nanoparticles in Hybridized Perovskite Solar Cell—Various Channels of Plasmon Photovoltaic Effect |
title_fullStr | Application of Core–Shell Metallic Nanoparticles in Hybridized Perovskite Solar Cell—Various Channels of Plasmon Photovoltaic Effect |
title_full_unstemmed | Application of Core–Shell Metallic Nanoparticles in Hybridized Perovskite Solar Cell—Various Channels of Plasmon Photovoltaic Effect |
title_short | Application of Core–Shell Metallic Nanoparticles in Hybridized Perovskite Solar Cell—Various Channels of Plasmon Photovoltaic Effect |
title_sort | application of core–shell metallic nanoparticles in hybridized perovskite solar cell—various channels of plasmon photovoltaic effect |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6804171/ https://www.ncbi.nlm.nih.gov/pubmed/31569454 http://dx.doi.org/10.3390/ma12193192 |
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