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The Influence of Zeolite (Sokyrnytsya Deposit) on the Physical and Chemical Resistance of a Magnesium Potassium Phosphate Compound for the Immobilization of High-Level Waste
The manuscript presents the results of the development of new material for high-level waste (HLW) management: the magnesium potassium phosphate (MKP) compound. The possibility of using zeolite (Sokyrnytsya deposit) to increase the mechanical, thermal, and hydrolytic resistance of this compound with...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6804266/ https://www.ncbi.nlm.nih.gov/pubmed/31547080 http://dx.doi.org/10.3390/molecules24193421 |
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author | Kulikova, Svetlana A. Vinokurov, Sergey E. |
author_facet | Kulikova, Svetlana A. Vinokurov, Sergey E. |
author_sort | Kulikova, Svetlana A. |
collection | PubMed |
description | The manuscript presents the results of the development of new material for high-level waste (HLW) management: the magnesium potassium phosphate (MKP) compound. The possibility of using zeolite (Sokyrnytsya deposit) to increase the mechanical, thermal, and hydrolytic resistance of this compound with immobilized HLW was studied. The main component of the used natural zeolite is a mineral of the clinoptilolite–heulandite series, and quartz, microcline, and clay minerals (illite, sepiolite, and smectite) are present as impurities. The compressive strength of the compound, containing at least 4.2 wt % zeolite, is about 25 MPa. Compound containing 28.6 wt % zeolite retains high compressive strength (at least 9.0 MPa), even after heat treatment at 450 °C. The adding of zeolite to the composition of the compound increases its hydrolytic stability, while the leaching rate of the mobile nuclides (137)Cs and (90)Sr decreases up to one order of values. Differential leaching rate of radionuclides from the compound containing 28.6 wt % zeolite is 2.6 × 10(−7) for (137)Cs, 2.9 × 10(−6) for (90)Sr, 1.7 × 10(−9) for (239)Pu, and 2.9 × 10(−9) g/(cm(2)∙day) for (241)Am. Thus, the properties of the resulting compound correspond to the requirements for solidified HLW in Russia. |
format | Online Article Text |
id | pubmed-6804266 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-68042662019-11-18 The Influence of Zeolite (Sokyrnytsya Deposit) on the Physical and Chemical Resistance of a Magnesium Potassium Phosphate Compound for the Immobilization of High-Level Waste Kulikova, Svetlana A. Vinokurov, Sergey E. Molecules Article The manuscript presents the results of the development of new material for high-level waste (HLW) management: the magnesium potassium phosphate (MKP) compound. The possibility of using zeolite (Sokyrnytsya deposit) to increase the mechanical, thermal, and hydrolytic resistance of this compound with immobilized HLW was studied. The main component of the used natural zeolite is a mineral of the clinoptilolite–heulandite series, and quartz, microcline, and clay minerals (illite, sepiolite, and smectite) are present as impurities. The compressive strength of the compound, containing at least 4.2 wt % zeolite, is about 25 MPa. Compound containing 28.6 wt % zeolite retains high compressive strength (at least 9.0 MPa), even after heat treatment at 450 °C. The adding of zeolite to the composition of the compound increases its hydrolytic stability, while the leaching rate of the mobile nuclides (137)Cs and (90)Sr decreases up to one order of values. Differential leaching rate of radionuclides from the compound containing 28.6 wt % zeolite is 2.6 × 10(−7) for (137)Cs, 2.9 × 10(−6) for (90)Sr, 1.7 × 10(−9) for (239)Pu, and 2.9 × 10(−9) g/(cm(2)∙day) for (241)Am. Thus, the properties of the resulting compound correspond to the requirements for solidified HLW in Russia. MDPI 2019-09-20 /pmc/articles/PMC6804266/ /pubmed/31547080 http://dx.doi.org/10.3390/molecules24193421 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Kulikova, Svetlana A. Vinokurov, Sergey E. The Influence of Zeolite (Sokyrnytsya Deposit) on the Physical and Chemical Resistance of a Magnesium Potassium Phosphate Compound for the Immobilization of High-Level Waste |
title | The Influence of Zeolite (Sokyrnytsya Deposit) on the Physical and Chemical Resistance of a Magnesium Potassium Phosphate Compound for the Immobilization of High-Level Waste |
title_full | The Influence of Zeolite (Sokyrnytsya Deposit) on the Physical and Chemical Resistance of a Magnesium Potassium Phosphate Compound for the Immobilization of High-Level Waste |
title_fullStr | The Influence of Zeolite (Sokyrnytsya Deposit) on the Physical and Chemical Resistance of a Magnesium Potassium Phosphate Compound for the Immobilization of High-Level Waste |
title_full_unstemmed | The Influence of Zeolite (Sokyrnytsya Deposit) on the Physical and Chemical Resistance of a Magnesium Potassium Phosphate Compound for the Immobilization of High-Level Waste |
title_short | The Influence of Zeolite (Sokyrnytsya Deposit) on the Physical and Chemical Resistance of a Magnesium Potassium Phosphate Compound for the Immobilization of High-Level Waste |
title_sort | influence of zeolite (sokyrnytsya deposit) on the physical and chemical resistance of a magnesium potassium phosphate compound for the immobilization of high-level waste |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6804266/ https://www.ncbi.nlm.nih.gov/pubmed/31547080 http://dx.doi.org/10.3390/molecules24193421 |
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