Chemoselectivity in the Oxidation of Cycloalkenes with a Non-Heme Iron(IV)-Oxo-Chloride Complex: Epoxidation vs. Hydroxylation Selectivity

We report and analyze chemoselectivity in the gas phase reactions of cycloalkenes (cyclohexene, cycloheptene, cis-cyclooctene, 1,4-cyclohexadiene) with a non-heme iron(IV)-oxo complex [(PyTACN)Fe(O)(Cl)](+), which models the active species in iron-dependent halogenases. Unlike in the halogenases, we...

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Detalles Bibliográficos
Autores principales: Terencio, Thibault, Andris, Erik, Gamba, Ilaria, Srnec, Martin, Costas, Miquel, Roithová, Jana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2019
Materias:
Focus: Honoring Helmut Schwarzʻs Election to the National Academy of Sciences: Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6805805/
https://www.ncbi.nlm.nih.gov/pubmed/31399940
http://dx.doi.org/10.1007/s13361-019-02251-1

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6805805/
https://www.ncbi.nlm.nih.gov/pubmed/31399940
http://dx.doi.org/10.1007/s13361-019-02251-1

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