Close Encounters of the Weak Kind: Investigations of Electron–Electron Interactions between Dissimilar Spins in Hybrid Rotaxanes

[Image: see text] We report a family of hybrid [2]rotaxanes based on inorganic [Cr(7)NiF(8)(O(2)C(t)Bu)(16)](−) (“{Cr(7)Ni}”) rings templated about organic threads that are terminated at one end with pyridyl groups. These rotaxanes can be coordinated to [Cu(hfac)(2)] (where Hhfac = 1,1,1,5,5,5-hexaf...

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Detalles Bibliográficos
Autores principales: Lockyer, Selena J., Fielding, Alistair J., Whitehead, George F. S., Timco, Grigore A., Winpenny, Richard E. P., McInnes, Eric J. L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6814243/
https://www.ncbi.nlm.nih.gov/pubmed/31411874
http://dx.doi.org/10.1021/jacs.9b05590

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