Cargando…
The effect of alloying elements on the properties of pressed and non-pressed biodegradable Fe–Mn–Ag powder metallurgy alloys
Current trends in the biodegradable scaffold industry call for powder metallurgy methods in which compression cannot be applied due to the nature of the scaffold template itself and the need to retain the shape of an underlying template throughout the fabrication process. Iron alloys have been shown...
Autores principales: | , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6819825/ https://www.ncbi.nlm.nih.gov/pubmed/31687606 http://dx.doi.org/10.1016/j.heliyon.2019.e02522 |
_version_ | 1783463825016619008 |
---|---|
author | Caligari Conti, Malcolm Mallia, Bertram Sinagra, Emmanuel Schembri Wismayer, Pierre Buhagiar, Joseph Vella, Daniel |
author_facet | Caligari Conti, Malcolm Mallia, Bertram Sinagra, Emmanuel Schembri Wismayer, Pierre Buhagiar, Joseph Vella, Daniel |
author_sort | Caligari Conti, Malcolm |
collection | PubMed |
description | Current trends in the biodegradable scaffold industry call for powder metallurgy methods in which compression cannot be applied due to the nature of the scaffold template itself and the need to retain the shape of an underlying template throughout the fabrication process. Iron alloys have been shown to be good candidates for biomedical applications where load support is required. Fe–Mn alloys were researched extensively for this purpose. Current research shows that all metallurgical characterisation and corrosion test on Fe–Mn and Fe–Mn–Ag non pre-alloyed powder alloys are performed on alloys which are initially pressed into greens and subsequently sintered. In order to combine the cutting-edge field of biodegradable metallic alloys with scaffold production, metallurgical characterisation of pressed and non-pressed Fe, Fe–Mn and Fe–Mn–Ag sintered elemental powder compacts was carried out in this study. This was performed along with determination of the corrosion rate of the same alloys in in vitro mimicking solutions. These solutions were synthesised to mimic the osteo environment in which the final scaffolds are to be used. Both pressed and non-pressed alloys formed an austenite phase under the right sintering conditions. The corrosion rate of the non-pressed alloy was greater than that of its pressed counterpart. In a potentiodynamic testing scenario, addition of silver to the alloy formed a separate silver phase which galvanically increased the corrosion rate of the pressed alloy. This result wasn't replicated in the non-pressed alloys in which the corrosion rate was seen to remain similar to the non-silver-bearing alloy counterparts. |
format | Online Article Text |
id | pubmed-6819825 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | Elsevier |
record_format | MEDLINE/PubMed |
spelling | pubmed-68198252019-11-04 The effect of alloying elements on the properties of pressed and non-pressed biodegradable Fe–Mn–Ag powder metallurgy alloys Caligari Conti, Malcolm Mallia, Bertram Sinagra, Emmanuel Schembri Wismayer, Pierre Buhagiar, Joseph Vella, Daniel Heliyon Article Current trends in the biodegradable scaffold industry call for powder metallurgy methods in which compression cannot be applied due to the nature of the scaffold template itself and the need to retain the shape of an underlying template throughout the fabrication process. Iron alloys have been shown to be good candidates for biomedical applications where load support is required. Fe–Mn alloys were researched extensively for this purpose. Current research shows that all metallurgical characterisation and corrosion test on Fe–Mn and Fe–Mn–Ag non pre-alloyed powder alloys are performed on alloys which are initially pressed into greens and subsequently sintered. In order to combine the cutting-edge field of biodegradable metallic alloys with scaffold production, metallurgical characterisation of pressed and non-pressed Fe, Fe–Mn and Fe–Mn–Ag sintered elemental powder compacts was carried out in this study. This was performed along with determination of the corrosion rate of the same alloys in in vitro mimicking solutions. These solutions were synthesised to mimic the osteo environment in which the final scaffolds are to be used. Both pressed and non-pressed alloys formed an austenite phase under the right sintering conditions. The corrosion rate of the non-pressed alloy was greater than that of its pressed counterpart. In a potentiodynamic testing scenario, addition of silver to the alloy formed a separate silver phase which galvanically increased the corrosion rate of the pressed alloy. This result wasn't replicated in the non-pressed alloys in which the corrosion rate was seen to remain similar to the non-silver-bearing alloy counterparts. Elsevier 2019-09-26 /pmc/articles/PMC6819825/ /pubmed/31687606 http://dx.doi.org/10.1016/j.heliyon.2019.e02522 Text en © 2019 The Author(s) http://creativecommons.org/licenses/by-nc-nd/4.0/ This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Article Caligari Conti, Malcolm Mallia, Bertram Sinagra, Emmanuel Schembri Wismayer, Pierre Buhagiar, Joseph Vella, Daniel The effect of alloying elements on the properties of pressed and non-pressed biodegradable Fe–Mn–Ag powder metallurgy alloys |
title | The effect of alloying elements on the properties of pressed and non-pressed biodegradable Fe–Mn–Ag powder metallurgy alloys |
title_full | The effect of alloying elements on the properties of pressed and non-pressed biodegradable Fe–Mn–Ag powder metallurgy alloys |
title_fullStr | The effect of alloying elements on the properties of pressed and non-pressed biodegradable Fe–Mn–Ag powder metallurgy alloys |
title_full_unstemmed | The effect of alloying elements on the properties of pressed and non-pressed biodegradable Fe–Mn–Ag powder metallurgy alloys |
title_short | The effect of alloying elements on the properties of pressed and non-pressed biodegradable Fe–Mn–Ag powder metallurgy alloys |
title_sort | effect of alloying elements on the properties of pressed and non-pressed biodegradable fe–mn–ag powder metallurgy alloys |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6819825/ https://www.ncbi.nlm.nih.gov/pubmed/31687606 http://dx.doi.org/10.1016/j.heliyon.2019.e02522 |
work_keys_str_mv | AT caligaricontimalcolm theeffectofalloyingelementsonthepropertiesofpressedandnonpressedbiodegradablefemnagpowdermetallurgyalloys AT malliabertram theeffectofalloyingelementsonthepropertiesofpressedandnonpressedbiodegradablefemnagpowdermetallurgyalloys AT sinagraemmanuel theeffectofalloyingelementsonthepropertiesofpressedandnonpressedbiodegradablefemnagpowdermetallurgyalloys AT schembriwismayerpierre theeffectofalloyingelementsonthepropertiesofpressedandnonpressedbiodegradablefemnagpowdermetallurgyalloys AT buhagiarjoseph theeffectofalloyingelementsonthepropertiesofpressedandnonpressedbiodegradablefemnagpowdermetallurgyalloys AT velladaniel theeffectofalloyingelementsonthepropertiesofpressedandnonpressedbiodegradablefemnagpowdermetallurgyalloys AT caligaricontimalcolm effectofalloyingelementsonthepropertiesofpressedandnonpressedbiodegradablefemnagpowdermetallurgyalloys AT malliabertram effectofalloyingelementsonthepropertiesofpressedandnonpressedbiodegradablefemnagpowdermetallurgyalloys AT sinagraemmanuel effectofalloyingelementsonthepropertiesofpressedandnonpressedbiodegradablefemnagpowdermetallurgyalloys AT schembriwismayerpierre effectofalloyingelementsonthepropertiesofpressedandnonpressedbiodegradablefemnagpowdermetallurgyalloys AT buhagiarjoseph effectofalloyingelementsonthepropertiesofpressedandnonpressedbiodegradablefemnagpowdermetallurgyalloys AT velladaniel effectofalloyingelementsonthepropertiesofpressedandnonpressedbiodegradablefemnagpowdermetallurgyalloys |