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Practical and stereoselective electrocatalytic 1,2-diamination of alkenes

The 1,2-diamine motif is widely present in natural products, pharmaceutical compounds, and catalysts used in asymmetric synthesis. The simultaneous introduction of two amino groups across an alkene feedstock is an appealing yet challenging approach for the synthesis of 1,2-diamines, primarily due to...

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Detalles Bibliográficos
Autores principales: Cai, Chen-Yan, Shu, Xiao-Min, Xu, Hai-Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6823458/
https://www.ncbi.nlm.nih.gov/pubmed/31672991
http://dx.doi.org/10.1038/s41467-019-13024-5