Cu(II)-Catalyzed Homocouplings of (Hetero)Arylboronic Acids with the Assistance of 2-O-Methyl-d-Glucopyranose

This is the first report of a natural ligand improving the copper-catalyzed homocouplings of (hetero)arylboronic acids. Various important synthetic biaryl intermediates in organic synthesis could be assembled via this method. To gain insight into this reaction, in situ React IR technology was used t...

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Detalles Bibliográficos
Autores principales: Yuan, Chunling, Zheng, Li, Zhao, Yingdai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6832226/
https://www.ncbi.nlm.nih.gov/pubmed/31614791
http://dx.doi.org/10.3390/molecules24203678
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author Yuan, Chunling
Zheng, Li
Zhao, Yingdai
author_facet Yuan, Chunling
Zheng, Li
Zhao, Yingdai
author_sort Yuan, Chunling
collection PubMed
description This is the first report of a natural ligand improving the copper-catalyzed homocouplings of (hetero)arylboronic acids. Various important synthetic biaryl intermediates in organic synthesis could be assembled via this method. To gain insight into this reaction, in situ React IR technology was used to confirm the effectivity of this catalyst system. This protocol could provide important biaryl compounds in high yields within a short time.
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spelling pubmed-68322262019-11-21 Cu(II)-Catalyzed Homocouplings of (Hetero)Arylboronic Acids with the Assistance of 2-O-Methyl-d-Glucopyranose Yuan, Chunling Zheng, Li Zhao, Yingdai Molecules Article This is the first report of a natural ligand improving the copper-catalyzed homocouplings of (hetero)arylboronic acids. Various important synthetic biaryl intermediates in organic synthesis could be assembled via this method. To gain insight into this reaction, in situ React IR technology was used to confirm the effectivity of this catalyst system. This protocol could provide important biaryl compounds in high yields within a short time. MDPI 2019-10-12 /pmc/articles/PMC6832226/ /pubmed/31614791 http://dx.doi.org/10.3390/molecules24203678 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Yuan, Chunling
Zheng, Li
Zhao, Yingdai
Cu(II)-Catalyzed Homocouplings of (Hetero)Arylboronic Acids with the Assistance of 2-O-Methyl-d-Glucopyranose
title Cu(II)-Catalyzed Homocouplings of (Hetero)Arylboronic Acids with the Assistance of 2-O-Methyl-d-Glucopyranose
title_full Cu(II)-Catalyzed Homocouplings of (Hetero)Arylboronic Acids with the Assistance of 2-O-Methyl-d-Glucopyranose
title_fullStr Cu(II)-Catalyzed Homocouplings of (Hetero)Arylboronic Acids with the Assistance of 2-O-Methyl-d-Glucopyranose
title_full_unstemmed Cu(II)-Catalyzed Homocouplings of (Hetero)Arylboronic Acids with the Assistance of 2-O-Methyl-d-Glucopyranose
title_short Cu(II)-Catalyzed Homocouplings of (Hetero)Arylboronic Acids with the Assistance of 2-O-Methyl-d-Glucopyranose
title_sort cu(ii)-catalyzed homocouplings of (hetero)arylboronic acids with the assistance of 2-o-methyl-d-glucopyranose
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6832226/
https://www.ncbi.nlm.nih.gov/pubmed/31614791
http://dx.doi.org/10.3390/molecules24203678
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