C–H-Bond Activation and Isoprene Polymerization Studies Applying Pentamethylcyclopentadienyl-Supported Rare-Earth-Metal Bis(Tetramethylaluminate) and Dimethyl Complexes

As previously shown for lutetium and yttrium, 1,2,3,4,5-pentamethylcyclopentadienyl (C(5)Me(5) = Cp*)-bearing rare-earth metal dimethyl half-sandwich complexes [Cp*LnMe(2)](3) are now also accessible for holmium, dysprosium, and terbium via tetramethylaluminato cleavage of [Cp*Ln(AlMe(4))(2)] with d...

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Detalles Bibliográficos
Autores principales: Hollfelder, Christoph O., Meermann-Zimmermann, Melanie, Spiridopoulos, Georgios, Werner, Daniel, Törnroos, Karl W., Maichle-Mössmer, Cäcilia, Anwander, Reiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6832758/
https://www.ncbi.nlm.nih.gov/pubmed/31618971
http://dx.doi.org/10.3390/molecules24203703

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6832758/
https://www.ncbi.nlm.nih.gov/pubmed/31618971
http://dx.doi.org/10.3390/molecules24203703

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