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C–H-Bond Activation and Isoprene Polymerization Studies Applying Pentamethylcyclopentadienyl-Supported Rare-Earth-Metal Bis(Tetramethylaluminate) and Dimethyl Complexes
As previously shown for lutetium and yttrium, 1,2,3,4,5-pentamethylcyclopentadienyl (C(5)Me(5) = Cp*)-bearing rare-earth metal dimethyl half-sandwich complexes [Cp*LnMe(2)](3) are now also accessible for holmium, dysprosium, and terbium via tetramethylaluminato cleavage of [Cp*Ln(AlMe(4))(2)] with d...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6832758/ https://www.ncbi.nlm.nih.gov/pubmed/31618971 http://dx.doi.org/10.3390/molecules24203703 |