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Preparation of a Novel Fracturing Fluid System with Excellent Elasticity and Low Friction
The quaternary polymer was synthesized by radical polymerization and characterized by (1)H NMR. The tests of critical associating concentration and SEM suggest that there is a multilayered and robust network structure in the polymer solution. An excellent elasticity in the polymer solution by the fi...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6835549/ https://www.ncbi.nlm.nih.gov/pubmed/31547216 http://dx.doi.org/10.3390/polym11101539 |
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author | Zhang, Yang Mao, Jincheng Zhao, Jinzhou Xu, Tao Du, Anqi Zhang, Zhaoyang Zhang, Wenlong Ma, Shaoyun |
author_facet | Zhang, Yang Mao, Jincheng Zhao, Jinzhou Xu, Tao Du, Anqi Zhang, Zhaoyang Zhang, Wenlong Ma, Shaoyun |
author_sort | Zhang, Yang |
collection | PubMed |
description | The quaternary polymer was synthesized by radical polymerization and characterized by (1)H NMR. The tests of critical associating concentration and SEM suggest that there is a multilayered and robust network structure in the polymer solution. An excellent elasticity in the polymer solution by the first normal stress difference, viscoelasticity, and thixotropy was observed. The critical crosslinker concentration of polymer with sodium dodecyl sulfate and its interaction mechanism were investigated. According to the reaction kinetics, the supramolecular structure had the lowest activation energy, stable network structure, and greater thermal stability. Then the polymer was employed in the fracturing fluid due to its excellent elasticity using the intermolecular forces, which showed superior sand suspension capacity by dynamic sand suspension measurement. Meanwhile, a theoretical analysis was proposed as to why polymer solution has excellent suspension and drag reduction properties. Therefore, this polymer could be an alternative in many fields, especially in fracking, which is significant for the development of oil and gas resources in deep wells. |
format | Online Article Text |
id | pubmed-6835549 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-68355492019-11-25 Preparation of a Novel Fracturing Fluid System with Excellent Elasticity and Low Friction Zhang, Yang Mao, Jincheng Zhao, Jinzhou Xu, Tao Du, Anqi Zhang, Zhaoyang Zhang, Wenlong Ma, Shaoyun Polymers (Basel) Article The quaternary polymer was synthesized by radical polymerization and characterized by (1)H NMR. The tests of critical associating concentration and SEM suggest that there is a multilayered and robust network structure in the polymer solution. An excellent elasticity in the polymer solution by the first normal stress difference, viscoelasticity, and thixotropy was observed. The critical crosslinker concentration of polymer with sodium dodecyl sulfate and its interaction mechanism were investigated. According to the reaction kinetics, the supramolecular structure had the lowest activation energy, stable network structure, and greater thermal stability. Then the polymer was employed in the fracturing fluid due to its excellent elasticity using the intermolecular forces, which showed superior sand suspension capacity by dynamic sand suspension measurement. Meanwhile, a theoretical analysis was proposed as to why polymer solution has excellent suspension and drag reduction properties. Therefore, this polymer could be an alternative in many fields, especially in fracking, which is significant for the development of oil and gas resources in deep wells. MDPI 2019-09-20 /pmc/articles/PMC6835549/ /pubmed/31547216 http://dx.doi.org/10.3390/polym11101539 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Zhang, Yang Mao, Jincheng Zhao, Jinzhou Xu, Tao Du, Anqi Zhang, Zhaoyang Zhang, Wenlong Ma, Shaoyun Preparation of a Novel Fracturing Fluid System with Excellent Elasticity and Low Friction |
title | Preparation of a Novel Fracturing Fluid System with Excellent Elasticity and Low Friction |
title_full | Preparation of a Novel Fracturing Fluid System with Excellent Elasticity and Low Friction |
title_fullStr | Preparation of a Novel Fracturing Fluid System with Excellent Elasticity and Low Friction |
title_full_unstemmed | Preparation of a Novel Fracturing Fluid System with Excellent Elasticity and Low Friction |
title_short | Preparation of a Novel Fracturing Fluid System with Excellent Elasticity and Low Friction |
title_sort | preparation of a novel fracturing fluid system with excellent elasticity and low friction |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6835549/ https://www.ncbi.nlm.nih.gov/pubmed/31547216 http://dx.doi.org/10.3390/polym11101539 |
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