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Steric and electronic control of an ultrafast isomerization

Synthetic control of the influence of steric and electronic factors on the ultrafast (picosecond) isomerization of penta-coordinate ruthenium dithietene complexes (Ru((CF(3))(2)C(2)S(2))(CO)(L)(2), where L = a monodentate phosphine ligand) is reported. Seven new ruthenium dithietene complexes were p...

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Detalles Bibliográficos
Autores principales: Porter, Tyler M., Ostericher, Andrew L., Kubiak, Clifford P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6836746/
https://www.ncbi.nlm.nih.gov/pubmed/31853348
http://dx.doi.org/10.1039/c9sc02359c