Stereodynamical control of product branching in multi-channel barrierless hydrogen abstraction of CH(3)OH by F

Hydrogen abstraction from methanol (CH(3)OH) by F atoms presents an ideal proving ground to investigate dynamics of multi-channel reactions, because two types of hydrogen can be abstracted from the methanol molecule leading to the HF + CH(3)O and HF + CH(2)OH products. Using the quasi-classical trajectory approach on a globally accurate potential energy surface based on high-level ab initio calculations, this work reports a comprehensive dynamical investigation of this multi-channel reaction, yielding measurable attributes including integral and differential cross sections, as well as branching ratios. It is shown that while complex-forming and direct mechanisms coexist at low collision energies, these barrierless reaction channels are dominated at high energies by the direct mechanism, in which the reaction is only possible for trajectories entering into the respective dynamical cones of acceptance. Perhaps more importantly, the non-statistical product branching is found to be dictated by unique stereodynamics in the entrance channels.