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Conceptual similarities between zeolites and artificial enzymes

By using a Diels–Alder (DA) reaction as a base case, we show that a pure silica zeolite acting as an entropy-trapping scaffold can be synthesized with an organic structure directing agent (OSDA) analogue of the transition state (TS) of the DA reaction. A cavity stabilization of the TS is observed wi...

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Detalles Bibliográficos
Autores principales:	Gallego, Eva M., Paris, Cecilia, Cantín, Ángel, Moliner, Manuel, Corma, Avelino
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6837030/ https://www.ncbi.nlm.nih.gov/pubmed/31853356 http://dx.doi.org/10.1039/c9sc02477h

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