Carbide clusterfullerene DyYTiC@C(80) featuring three different metals in the endohedral cluster and its single-ion magnetism†

Carbide clusterfullerene DyYTiC@C(80)-I(h) with three different metal atoms in the endohedral cluster is obtained by arc-discharge synthesis with methane as reactive gas and is successfully isolated by HPLC. The compound shows single-molecule magnetism (SMM) with magnetic hysteresis below 8 K. The S...

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Detalles Bibliográficos
Autores principales: Brandenburg, Ariane, Krylov, Denis S., Beger, Alexander, Wolter, Anja U. B., Büchner, Bernd, Popov, Alexey A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6839965/
https://www.ncbi.nlm.nih.gov/pubmed/30087957
http://dx.doi.org/10.1039/c8cc04736g
Descripción
Sumario:Carbide clusterfullerene DyYTiC@C(80)-I(h) with three different metal atoms in the endohedral cluster is obtained by arc-discharge synthesis with methane as reactive gas and is successfully isolated by HPLC. The compound shows single-molecule magnetism (SMM) with magnetic hysteresis below 8 K. The SMM properties of DyYTiC@C(80) are compared to those of DySc(2)N@C(80) and the influence of the central atom in the endohedral cluster is analyzed.

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