Carbide clusterfullerene DyYTiC@C(80) featuring three different metals in the endohedral cluster and its single-ion magnetism†

Carbide clusterfullerene DyYTiC@C(80)-I(h) with three different metal atoms in the endohedral cluster is obtained by arc-discharge synthesis with methane as reactive gas and is successfully isolated by HPLC. The compound shows single-molecule magnetism (SMM) with magnetic hysteresis below 8 K. The S...

Descripción completa

Detalles Bibliográficos
Autores principales: Brandenburg, Ariane, Krylov, Denis S., Beger, Alexander, Wolter, Anja U. B., Büchner, Bernd, Popov, Alexey A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6839965/
https://www.ncbi.nlm.nih.gov/pubmed/30087957
http://dx.doi.org/10.1039/c8cc04736g
_version_ 1783467516074393600
author Brandenburg, Ariane
Krylov, Denis S.
Beger, Alexander
Wolter, Anja U. B.
Büchner, Bernd
Popov, Alexey A.
author_facet Brandenburg, Ariane
Krylov, Denis S.
Beger, Alexander
Wolter, Anja U. B.
Büchner, Bernd
Popov, Alexey A.
author_sort Brandenburg, Ariane
collection PubMed
description Carbide clusterfullerene DyYTiC@C(80)-I(h) with three different metal atoms in the endohedral cluster is obtained by arc-discharge synthesis with methane as reactive gas and is successfully isolated by HPLC. The compound shows single-molecule magnetism (SMM) with magnetic hysteresis below 8 K. The SMM properties of DyYTiC@C(80) are compared to those of DySc(2)N@C(80) and the influence of the central atom in the endohedral cluster is analyzed.
format Online
Article
Text
id pubmed-6839965
institution National Center for Biotechnology Information
language English
publishDate 2018
record_format MEDLINE/PubMed
spelling pubmed-68399652019-11-08 Carbide clusterfullerene DyYTiC@C(80) featuring three different metals in the endohedral cluster and its single-ion magnetism† Brandenburg, Ariane Krylov, Denis S. Beger, Alexander Wolter, Anja U. B. Büchner, Bernd Popov, Alexey A. Chem Commun (Camb) Article Carbide clusterfullerene DyYTiC@C(80)-I(h) with three different metal atoms in the endohedral cluster is obtained by arc-discharge synthesis with methane as reactive gas and is successfully isolated by HPLC. The compound shows single-molecule magnetism (SMM) with magnetic hysteresis below 8 K. The SMM properties of DyYTiC@C(80) are compared to those of DySc(2)N@C(80) and the influence of the central atom in the endohedral cluster is analyzed. 2018-09-20 /pmc/articles/PMC6839965/ /pubmed/30087957 http://dx.doi.org/10.1039/c8cc04736g Text en http://creativecommons.org/licenses/by/3.0/ This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/) .
spellingShingle Article
Brandenburg, Ariane
Krylov, Denis S.
Beger, Alexander
Wolter, Anja U. B.
Büchner, Bernd
Popov, Alexey A.
Carbide clusterfullerene DyYTiC@C(80) featuring three different metals in the endohedral cluster and its single-ion magnetism†
title Carbide clusterfullerene DyYTiC@C(80) featuring three different metals in the endohedral cluster and its single-ion magnetism†
title_full Carbide clusterfullerene DyYTiC@C(80) featuring three different metals in the endohedral cluster and its single-ion magnetism†
title_fullStr Carbide clusterfullerene DyYTiC@C(80) featuring three different metals in the endohedral cluster and its single-ion magnetism†
title_full_unstemmed Carbide clusterfullerene DyYTiC@C(80) featuring three different metals in the endohedral cluster and its single-ion magnetism†
title_short Carbide clusterfullerene DyYTiC@C(80) featuring three different metals in the endohedral cluster and its single-ion magnetism†
title_sort carbide clusterfullerene dyytic@c(80) featuring three different metals in the endohedral cluster and its single-ion magnetism†
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6839965/
https://www.ncbi.nlm.nih.gov/pubmed/30087957
http://dx.doi.org/10.1039/c8cc04736g
work_keys_str_mv AT brandenburgariane carbideclusterfullerenedyyticc80featuringthreedifferentmetalsintheendohedralclusteranditssingleionmagnetism
AT krylovdeniss carbideclusterfullerenedyyticc80featuringthreedifferentmetalsintheendohedralclusteranditssingleionmagnetism
AT begeralexander carbideclusterfullerenedyyticc80featuringthreedifferentmetalsintheendohedralclusteranditssingleionmagnetism
AT wolteranjaub carbideclusterfullerenedyyticc80featuringthreedifferentmetalsintheendohedralclusteranditssingleionmagnetism
AT buchnerbernd carbideclusterfullerenedyyticc80featuringthreedifferentmetalsintheendohedralclusteranditssingleionmagnetism
AT popovalexeya carbideclusterfullerenedyyticc80featuringthreedifferentmetalsintheendohedralclusteranditssingleionmagnetism

Ejemplares similares