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Low temperature synthesis via molten-salt method of r-BN nanoflakes, and their properties

r-BN nanoflakes were synthesized using KBH(4) and NH(4)Cl as the main raw material in a high-purity nitrogen atmosphere. The effects of salt and salt-free conditions and heating temperature on the synthesis of BN were studied. The molten-salt method was used to synthesize BN at 650 °C, which was 250...

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Detalles Bibliográficos
Autores principales: Chen, Yang, Wang, Xing, Yu, Chao, Ding, Jun, Deng, Chengji, Zhu, Hongxi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6841957/
https://www.ncbi.nlm.nih.gov/pubmed/31704975
http://dx.doi.org/10.1038/s41598-019-52788-0
Descripción
Sumario:r-BN nanoflakes were synthesized using KBH(4) and NH(4)Cl as the main raw material in a high-purity nitrogen atmosphere. The effects of salt and salt-free conditions and heating temperature on the synthesis of BN were studied. The molten-salt method was used to synthesize BN at 650 °C, which was 250 °C lower than the BN synthesis method without salt. Furthermore, at 1000 °C the prepared flake-like BN crystals showed good crystallinity, uniform morphology, a particle diameter of 200–300 nm, and a thickness of 40–70 nm. Moreover, the specific surface area of BN was 294.26 m(2)/g. In addition, the BN synthesized at 1100 °C had a large elastic modulus value and good oxidation resistance.