Cargando…
Low temperature synthesis via molten-salt method of r-BN nanoflakes, and their properties
r-BN nanoflakes were synthesized using KBH(4) and NH(4)Cl as the main raw material in a high-purity nitrogen atmosphere. The effects of salt and salt-free conditions and heating temperature on the synthesis of BN were studied. The molten-salt method was used to synthesize BN at 650 °C, which was 250...
Autores principales: | , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6841957/ https://www.ncbi.nlm.nih.gov/pubmed/31704975 http://dx.doi.org/10.1038/s41598-019-52788-0 |
Sumario: | r-BN nanoflakes were synthesized using KBH(4) and NH(4)Cl as the main raw material in a high-purity nitrogen atmosphere. The effects of salt and salt-free conditions and heating temperature on the synthesis of BN were studied. The molten-salt method was used to synthesize BN at 650 °C, which was 250 °C lower than the BN synthesis method without salt. Furthermore, at 1000 °C the prepared flake-like BN crystals showed good crystallinity, uniform morphology, a particle diameter of 200–300 nm, and a thickness of 40–70 nm. Moreover, the specific surface area of BN was 294.26 m(2)/g. In addition, the BN synthesized at 1100 °C had a large elastic modulus value and good oxidation resistance. |
---|