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Low temperature synthesis via molten-salt method of r-BN nanoflakes, and their properties

r-BN nanoflakes were synthesized using KBH(4) and NH(4)Cl as the main raw material in a high-purity nitrogen atmosphere. The effects of salt and salt-free conditions and heating temperature on the synthesis of BN were studied. The molten-salt method was used to synthesize BN at 650 °C, which was 250...

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Autores principales: Chen, Yang, Wang, Xing, Yu, Chao, Ding, Jun, Deng, Chengji, Zhu, Hongxi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6841957/
https://www.ncbi.nlm.nih.gov/pubmed/31704975
http://dx.doi.org/10.1038/s41598-019-52788-0
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author Chen, Yang
Wang, Xing
Yu, Chao
Ding, Jun
Deng, Chengji
Zhu, Hongxi
author_facet Chen, Yang
Wang, Xing
Yu, Chao
Ding, Jun
Deng, Chengji
Zhu, Hongxi
author_sort Chen, Yang
collection PubMed
description r-BN nanoflakes were synthesized using KBH(4) and NH(4)Cl as the main raw material in a high-purity nitrogen atmosphere. The effects of salt and salt-free conditions and heating temperature on the synthesis of BN were studied. The molten-salt method was used to synthesize BN at 650 °C, which was 250 °C lower than the BN synthesis method without salt. Furthermore, at 1000 °C the prepared flake-like BN crystals showed good crystallinity, uniform morphology, a particle diameter of 200–300 nm, and a thickness of 40–70 nm. Moreover, the specific surface area of BN was 294.26 m(2)/g. In addition, the BN synthesized at 1100 °C had a large elastic modulus value and good oxidation resistance.
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spelling pubmed-68419572019-11-14 Low temperature synthesis via molten-salt method of r-BN nanoflakes, and their properties Chen, Yang Wang, Xing Yu, Chao Ding, Jun Deng, Chengji Zhu, Hongxi Sci Rep Article r-BN nanoflakes were synthesized using KBH(4) and NH(4)Cl as the main raw material in a high-purity nitrogen atmosphere. The effects of salt and salt-free conditions and heating temperature on the synthesis of BN were studied. The molten-salt method was used to synthesize BN at 650 °C, which was 250 °C lower than the BN synthesis method without salt. Furthermore, at 1000 °C the prepared flake-like BN crystals showed good crystallinity, uniform morphology, a particle diameter of 200–300 nm, and a thickness of 40–70 nm. Moreover, the specific surface area of BN was 294.26 m(2)/g. In addition, the BN synthesized at 1100 °C had a large elastic modulus value and good oxidation resistance. Nature Publishing Group UK 2019-11-08 /pmc/articles/PMC6841957/ /pubmed/31704975 http://dx.doi.org/10.1038/s41598-019-52788-0 Text en © The Author(s) 2019 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Chen, Yang
Wang, Xing
Yu, Chao
Ding, Jun
Deng, Chengji
Zhu, Hongxi
Low temperature synthesis via molten-salt method of r-BN nanoflakes, and their properties
title Low temperature synthesis via molten-salt method of r-BN nanoflakes, and their properties
title_full Low temperature synthesis via molten-salt method of r-BN nanoflakes, and their properties
title_fullStr Low temperature synthesis via molten-salt method of r-BN nanoflakes, and their properties
title_full_unstemmed Low temperature synthesis via molten-salt method of r-BN nanoflakes, and their properties
title_short Low temperature synthesis via molten-salt method of r-BN nanoflakes, and their properties
title_sort low temperature synthesis via molten-salt method of r-bn nanoflakes, and their properties
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6841957/
https://www.ncbi.nlm.nih.gov/pubmed/31704975
http://dx.doi.org/10.1038/s41598-019-52788-0
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