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Highly Porous Willow Wood-Derived Activated Carbon for High-Performance Supercapacitor Electrodes

[Image: see text] In this study, we present willow wood as a new low-cost, renewable, and sustainable biomass source for the production of a highly porous activated carbon for application in energy storage devices. The obtained activated carbon showed favorable features required for excellent electr...

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Autores principales: Phiri, Josphat, Dou, Jinze, Vuorinen, Tapani, Gane, Patrick A. C., Maloney, Thaddeus C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6843703/
https://www.ncbi.nlm.nih.gov/pubmed/31720513
http://dx.doi.org/10.1021/acsomega.9b01977
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author Phiri, Josphat
Dou, Jinze
Vuorinen, Tapani
Gane, Patrick A. C.
Maloney, Thaddeus C.
author_facet Phiri, Josphat
Dou, Jinze
Vuorinen, Tapani
Gane, Patrick A. C.
Maloney, Thaddeus C.
author_sort Phiri, Josphat
collection PubMed
description [Image: see text] In this study, we present willow wood as a new low-cost, renewable, and sustainable biomass source for the production of a highly porous activated carbon for application in energy storage devices. The obtained activated carbon showed favorable features required for excellent electrochemical performance such as high surface area (∼2 800 m(2) g(–1)) and pore volume (1.45 cm(3) g(–1)), with coexistence of micropores and mesopores. This carbon material was tested as an electrode for supercapacitor application and showed a high specific capacitance of 394 F g(–1) at a current density of 1 A g(–1) and good cycling stability, retaining ∼94% capacitance after 5 000 cycles (at a current density of 5 A g(–1)) in 6 M KOH electrolyte. The prepared carbon material also showed an excellent rate performance in a symmetrical two-electrode full cell configuration using 1 M Na(2)SO(4) electrolyte, in a high working voltage of 1.8 V. The maximum energy density and power density of the fabricated symmetric cell reach 23 W h kg(–1) and 10 000 W kg(–1), respectively. These results demonstrate that willow wood can serve as a low-cost carbon feedstock for production of high-performance electrode material for supercapacitors.
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spelling pubmed-68437032019-11-12 Highly Porous Willow Wood-Derived Activated Carbon for High-Performance Supercapacitor Electrodes Phiri, Josphat Dou, Jinze Vuorinen, Tapani Gane, Patrick A. C. Maloney, Thaddeus C. ACS Omega [Image: see text] In this study, we present willow wood as a new low-cost, renewable, and sustainable biomass source for the production of a highly porous activated carbon for application in energy storage devices. The obtained activated carbon showed favorable features required for excellent electrochemical performance such as high surface area (∼2 800 m(2) g(–1)) and pore volume (1.45 cm(3) g(–1)), with coexistence of micropores and mesopores. This carbon material was tested as an electrode for supercapacitor application and showed a high specific capacitance of 394 F g(–1) at a current density of 1 A g(–1) and good cycling stability, retaining ∼94% capacitance after 5 000 cycles (at a current density of 5 A g(–1)) in 6 M KOH electrolyte. The prepared carbon material also showed an excellent rate performance in a symmetrical two-electrode full cell configuration using 1 M Na(2)SO(4) electrolyte, in a high working voltage of 1.8 V. The maximum energy density and power density of the fabricated symmetric cell reach 23 W h kg(–1) and 10 000 W kg(–1), respectively. These results demonstrate that willow wood can serve as a low-cost carbon feedstock for production of high-performance electrode material for supercapacitors. American Chemical Society 2019-10-22 /pmc/articles/PMC6843703/ /pubmed/31720513 http://dx.doi.org/10.1021/acsomega.9b01977 Text en Copyright © 2019 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Phiri, Josphat
Dou, Jinze
Vuorinen, Tapani
Gane, Patrick A. C.
Maloney, Thaddeus C.
Highly Porous Willow Wood-Derived Activated Carbon for High-Performance Supercapacitor Electrodes
title Highly Porous Willow Wood-Derived Activated Carbon for High-Performance Supercapacitor Electrodes
title_full Highly Porous Willow Wood-Derived Activated Carbon for High-Performance Supercapacitor Electrodes
title_fullStr Highly Porous Willow Wood-Derived Activated Carbon for High-Performance Supercapacitor Electrodes
title_full_unstemmed Highly Porous Willow Wood-Derived Activated Carbon for High-Performance Supercapacitor Electrodes
title_short Highly Porous Willow Wood-Derived Activated Carbon for High-Performance Supercapacitor Electrodes
title_sort highly porous willow wood-derived activated carbon for high-performance supercapacitor electrodes
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6843703/
https://www.ncbi.nlm.nih.gov/pubmed/31720513
http://dx.doi.org/10.1021/acsomega.9b01977
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