Asymmetry in the Ligand Coordination Sphere of the [FeFe] Hydrogenase Active Site Is Reflected in the Magnetic Spin Interactions of the Aza-propanedithiolate Ligand

[Image: see text] [FeFe] hydrogenases are very active enzymes that catalyze the reversible conversion of molecular hydrogen into protons and electrons. Their active site, the H-cluster, contains a unique binuclear iron complex, [2Fe](H), with CN(–) and CO ligands as well as an aza-propane-dithiolate...

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Detalles Bibliográficos
Autores principales: Reijerse, Edward J., Pelmenschikov, Vladimir, Birrell, James A., Richers, Casseday P., Kaupp, Martin, Rauchfuss, Thomas B., Cramer, Stephen P., Lubitz, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6844125/
https://www.ncbi.nlm.nih.gov/pubmed/31580680
http://dx.doi.org/10.1021/acs.jpclett.9b02354

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