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Heating of Ti(3)C(2)T(x) MXene/polymer composites in response to Radio Frequency fields

Here we report for the first time that Ti(3)C(2)T(x)/polymer composite films rapidly heat when exposed to low-power radio frequency fields. Ti(3)C(2)T(x) MXenes possess a high dielectric loss tangent, which is correlated with this rapid heating under electromagnetic fields. Thermal imaging confirms...

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Autores principales: Habib, Touseef, Patil, Nutan, Zhao, Xiaofei, Prehn, Evan, Anas, Muhammad, Lutkenhaus, Jodie L., Radovic, Miladin, Green, Micah J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6848125/
https://www.ncbi.nlm.nih.gov/pubmed/31712667
http://dx.doi.org/10.1038/s41598-019-52972-2
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author Habib, Touseef
Patil, Nutan
Zhao, Xiaofei
Prehn, Evan
Anas, Muhammad
Lutkenhaus, Jodie L.
Radovic, Miladin
Green, Micah J.
author_facet Habib, Touseef
Patil, Nutan
Zhao, Xiaofei
Prehn, Evan
Anas, Muhammad
Lutkenhaus, Jodie L.
Radovic, Miladin
Green, Micah J.
author_sort Habib, Touseef
collection PubMed
description Here we report for the first time that Ti(3)C(2)T(x)/polymer composite films rapidly heat when exposed to low-power radio frequency fields. Ti(3)C(2)T(x) MXenes possess a high dielectric loss tangent, which is correlated with this rapid heating under electromagnetic fields. Thermal imaging confirms that these structures are capable of extraordinary heating rates (as high as 303 K/s) that are frequency- and concentration-dependent. At high loading (and high conductivity), Ti(3)C(2)T(x) MXene composites do not heat under RF fields due to reflection of electromagnetic waves, whereas composites with low conductivity do not heat due to the lack of an electrical percolating network. Composites with an intermediate loading and a conductivity between 10–1000 S m(−1) rapidly generate heat under RF fields. This finding unlocks a new property of Ti(3)C(2)T(x) MXenes and a new material for potential RF-based applications.
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spelling pubmed-68481252019-11-19 Heating of Ti(3)C(2)T(x) MXene/polymer composites in response to Radio Frequency fields Habib, Touseef Patil, Nutan Zhao, Xiaofei Prehn, Evan Anas, Muhammad Lutkenhaus, Jodie L. Radovic, Miladin Green, Micah J. Sci Rep Article Here we report for the first time that Ti(3)C(2)T(x)/polymer composite films rapidly heat when exposed to low-power radio frequency fields. Ti(3)C(2)T(x) MXenes possess a high dielectric loss tangent, which is correlated with this rapid heating under electromagnetic fields. Thermal imaging confirms that these structures are capable of extraordinary heating rates (as high as 303 K/s) that are frequency- and concentration-dependent. At high loading (and high conductivity), Ti(3)C(2)T(x) MXene composites do not heat under RF fields due to reflection of electromagnetic waves, whereas composites with low conductivity do not heat due to the lack of an electrical percolating network. Composites with an intermediate loading and a conductivity between 10–1000 S m(−1) rapidly generate heat under RF fields. This finding unlocks a new property of Ti(3)C(2)T(x) MXenes and a new material for potential RF-based applications. Nature Publishing Group UK 2019-11-11 /pmc/articles/PMC6848125/ /pubmed/31712667 http://dx.doi.org/10.1038/s41598-019-52972-2 Text en © The Author(s) 2019 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Habib, Touseef
Patil, Nutan
Zhao, Xiaofei
Prehn, Evan
Anas, Muhammad
Lutkenhaus, Jodie L.
Radovic, Miladin
Green, Micah J.
Heating of Ti(3)C(2)T(x) MXene/polymer composites in response to Radio Frequency fields
title Heating of Ti(3)C(2)T(x) MXene/polymer composites in response to Radio Frequency fields
title_full Heating of Ti(3)C(2)T(x) MXene/polymer composites in response to Radio Frequency fields
title_fullStr Heating of Ti(3)C(2)T(x) MXene/polymer composites in response to Radio Frequency fields
title_full_unstemmed Heating of Ti(3)C(2)T(x) MXene/polymer composites in response to Radio Frequency fields
title_short Heating of Ti(3)C(2)T(x) MXene/polymer composites in response to Radio Frequency fields
title_sort heating of ti(3)c(2)t(x) mxene/polymer composites in response to radio frequency fields
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6848125/
https://www.ncbi.nlm.nih.gov/pubmed/31712667
http://dx.doi.org/10.1038/s41598-019-52972-2
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