Egg Albumin-Assisted Hydrothermal Synthesis of Co(3)O(4) Quasi-Cubes as Superior Electrode Material for Supercapacitors with Excellent Performances

Novel Co(3)O(4) quasi-cubes with layered structure were obtained via two-step synthetic procedures. The precursors were initially prepared via hydrothermal reaction in the presence of egg albumin, and then the precursors were directly annealed at 300 °C in air to be converted into pure Co(3)O(4) powders. It was found that the size and morphology of final Co(3)O(4) products were greatly influenced by the amount of egg albumin and hydrothermal durations, respectively. Such layered Co(3)O(4) cubes possessed a mesoporous nature with a mean pore size of 5.58 nm and total specific surface area of 80.3 m(2)/g. A three-electrode system and 2 M of KOH aqueous electrolyte were employed to evaluate the electrochemical properties of these Co(3)O(4) cubes. The results indicated that a specific capacitance of 754 F g(−1) at 1 A g(−1) was achieved. In addition, the Co(3)O(4) cubes-modified electrode exhibited an excellent rate performance of 77% at 10 A g(−1) and superior cycling durability with 86.7% capacitance retention during 4000 repeated charge-discharge process at 5 A g(−1). Such high electrochemical performances suggest that these mesoporous Co(3)O(4) quasi-cubes can serve as an important electrode material for the next-generation advanced supercapacitors in the future.