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Phosphorus Post‐Functionalization of Diphosphahexaarenes
Diphosphahexaarenes are highly stable π‐extended frameworks containing two six‐membered phosphorus heterocycles that have emerged recently. Herein, we present a detailed investigation on the post‐functionalization reactions of their phosphorus centers with special emphasis on the selectivity of the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6851889/ https://www.ncbi.nlm.nih.gov/pubmed/31314930 http://dx.doi.org/10.1002/chem.201901837 |
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author | Hindenberg, Philip Rominger, Frank Romero‐Nieto, Carlos |
author_facet | Hindenberg, Philip Rominger, Frank Romero‐Nieto, Carlos |
author_sort | Hindenberg, Philip |
collection | PubMed |
description | Diphosphahexaarenes are highly stable π‐extended frameworks containing two six‐membered phosphorus heterocycles that have emerged recently. Herein, we present a detailed investigation on the post‐functionalization reactions of their phosphorus centers with special emphasis on the selectivity of the processes and the impact of the phosphorus functionalizations into the physicochemical properties. These studies reveal that indeed the phosphorus atoms of the diphosphahexaarenes are readily available to be functionalized with quaternizing and oxidizing agents as well as borane groups without compromising the stability of the system. In addition, the optoelectronic properties of the diphosphahexaarenes are impacted by the phosphorus post‐modifications. |
format | Online Article Text |
id | pubmed-6851889 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-68518892019-11-18 Phosphorus Post‐Functionalization of Diphosphahexaarenes Hindenberg, Philip Rominger, Frank Romero‐Nieto, Carlos Chemistry Full Papers Diphosphahexaarenes are highly stable π‐extended frameworks containing two six‐membered phosphorus heterocycles that have emerged recently. Herein, we present a detailed investigation on the post‐functionalization reactions of their phosphorus centers with special emphasis on the selectivity of the processes and the impact of the phosphorus functionalizations into the physicochemical properties. These studies reveal that indeed the phosphorus atoms of the diphosphahexaarenes are readily available to be functionalized with quaternizing and oxidizing agents as well as borane groups without compromising the stability of the system. In addition, the optoelectronic properties of the diphosphahexaarenes are impacted by the phosphorus post‐modifications. John Wiley and Sons Inc. 2019-08-21 2019-10-11 /pmc/articles/PMC6851889/ /pubmed/31314930 http://dx.doi.org/10.1002/chem.201901837 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. |
spellingShingle | Full Papers Hindenberg, Philip Rominger, Frank Romero‐Nieto, Carlos Phosphorus Post‐Functionalization of Diphosphahexaarenes |
title | Phosphorus Post‐Functionalization of Diphosphahexaarenes |
title_full | Phosphorus Post‐Functionalization of Diphosphahexaarenes |
title_fullStr | Phosphorus Post‐Functionalization of Diphosphahexaarenes |
title_full_unstemmed | Phosphorus Post‐Functionalization of Diphosphahexaarenes |
title_short | Phosphorus Post‐Functionalization of Diphosphahexaarenes |
title_sort | phosphorus post‐functionalization of diphosphahexaarenes |
topic | Full Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6851889/ https://www.ncbi.nlm.nih.gov/pubmed/31314930 http://dx.doi.org/10.1002/chem.201901837 |
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