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Single-ion anisotropy and exchange coupling in cobalt(ii)-radical complexes: insights from magnetic and ab initio studies
The concurrent effects of single-ion anisotropy and exchange interactions on the electronic structure and magnetization dynamics have been analyzed for a cobalt(ii)-semiquinonate complex. Analogs containing diamagnetic catecholate and tropolonate ligands were employed for comparison of the magnetic...
Autores principales: | Gransbury, Gemma K., Boulon, Marie-Emmanuelle, Mole, Richard A., Gable, Robert W., Moubaraki, Boujemaa, Murray, Keith S., Sorace, Lorenzo, Soncini, Alessandro, Boskovic, Colette |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6853083/ https://www.ncbi.nlm.nih.gov/pubmed/31803460 http://dx.doi.org/10.1039/c9sc00914k |
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