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Planar three-coordinate iron sulfide in a synthetic [4Fe-3S] cluster with biomimetic reactivity

Iron-sulfur clusters are emerging as reactive sites for the reduction of small-molecule substrates. However, the four-coordinate iron sites of typical iron-sulfur clusters rarely react with substrates, implicating three-coordinate iron. This idea is untested because fully sulfide-coordinated three-c...

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Detalles Bibliográficos
Autores principales:	DeRosha, Daniel E., Chilkuri, Vijay G., Van Stappen, Casey, Bill, Eckhard, Mercado, Brandon Q., DeBeer, Serena, Neese, Frank, Holland, Patrick L.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	2019
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6858550/ https://www.ncbi.nlm.nih.gov/pubmed/31611632 http://dx.doi.org/10.1038/s41557-019-0341-7

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