Nontoxic KBBF Family Member Zn(2)BO(3)(OH): Balance between Beneficial Layered Structure and Layer Tendency

The conflict between beneficial layered structure for performances and layered growth habits in KBe(2)BO(3)F(2) (KBBF) always restricts its practical applications. A beryllium‐free KBBF family member, Zn(2)BO(3)(OH), is explored to feature the same topological layer with KBBF by replacing [BeO(3)F](...

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Autores principales: Wang, Xuefei, Zhang, Fangfang, Gao, Le, Yang, Zhihua, Pan, Shilie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6864501/
https://www.ncbi.nlm.nih.gov/pubmed/31763150
http://dx.doi.org/10.1002/advs.201901679
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author Wang, Xuefei
Zhang, Fangfang
Gao, Le
Yang, Zhihua
Pan, Shilie
author_facet Wang, Xuefei
Zhang, Fangfang
Gao, Le
Yang, Zhihua
Pan, Shilie
author_sort Wang, Xuefei
collection PubMed
description The conflict between beneficial layered structure for performances and layered growth habits in KBe(2)BO(3)F(2) (KBBF) always restricts its practical applications. A beryllium‐free KBBF family member, Zn(2)BO(3)(OH), is explored to feature the same topological layer with KBBF by replacing [BeO(3)F](5−) with [ZnO(3)(OH)](5−) and excellent UV performances. It exhibits a second harmonic generation response of about 1.5 × KH(2)PO(4) with the UV cutoff edge of 204 nm. The birefringence of Zn(2)BO(3)(OH) in the visible region is about 0.067, which is larger than those of commercial UV crystals LiB(3)O(5), CsB(3)O(5), and CsLiB(6)O(10). Additionally, it has excellent thermal and water‐resistant stabilities. Owing to the removal of interlayer cations, Zn(2)BO(3)(OH) shows better growth habits than KBBF while achieving the balance between beneficial layered structure and layer tendency.
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spelling pubmed-68645012019-11-22 Nontoxic KBBF Family Member Zn(2)BO(3)(OH): Balance between Beneficial Layered Structure and Layer Tendency Wang, Xuefei Zhang, Fangfang Gao, Le Yang, Zhihua Pan, Shilie Adv Sci (Weinh) Communications The conflict between beneficial layered structure for performances and layered growth habits in KBe(2)BO(3)F(2) (KBBF) always restricts its practical applications. A beryllium‐free KBBF family member, Zn(2)BO(3)(OH), is explored to feature the same topological layer with KBBF by replacing [BeO(3)F](5−) with [ZnO(3)(OH)](5−) and excellent UV performances. It exhibits a second harmonic generation response of about 1.5 × KH(2)PO(4) with the UV cutoff edge of 204 nm. The birefringence of Zn(2)BO(3)(OH) in the visible region is about 0.067, which is larger than those of commercial UV crystals LiB(3)O(5), CsB(3)O(5), and CsLiB(6)O(10). Additionally, it has excellent thermal and water‐resistant stabilities. Owing to the removal of interlayer cations, Zn(2)BO(3)(OH) shows better growth habits than KBBF while achieving the balance between beneficial layered structure and layer tendency. John Wiley and Sons Inc. 2019-09-16 /pmc/articles/PMC6864501/ /pubmed/31763150 http://dx.doi.org/10.1002/advs.201901679 Text en © 2019 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Wang, Xuefei
Zhang, Fangfang
Gao, Le
Yang, Zhihua
Pan, Shilie
Nontoxic KBBF Family Member Zn(2)BO(3)(OH): Balance between Beneficial Layered Structure and Layer Tendency
title Nontoxic KBBF Family Member Zn(2)BO(3)(OH): Balance between Beneficial Layered Structure and Layer Tendency
title_full Nontoxic KBBF Family Member Zn(2)BO(3)(OH): Balance between Beneficial Layered Structure and Layer Tendency
title_fullStr Nontoxic KBBF Family Member Zn(2)BO(3)(OH): Balance between Beneficial Layered Structure and Layer Tendency
title_full_unstemmed Nontoxic KBBF Family Member Zn(2)BO(3)(OH): Balance between Beneficial Layered Structure and Layer Tendency
title_short Nontoxic KBBF Family Member Zn(2)BO(3)(OH): Balance between Beneficial Layered Structure and Layer Tendency
title_sort nontoxic kbbf family member zn(2)bo(3)(oh): balance between beneficial layered structure and layer tendency
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6864501/
https://www.ncbi.nlm.nih.gov/pubmed/31763150
http://dx.doi.org/10.1002/advs.201901679
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