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Ultrafast Detection of Low Acetone Concentration Displayed by Au-Loaded LaFeO(3) Nanobelts owing to Synergetic Effects of Porous 1D Morphology and Catalytic Activity of Au Nanoparticles

[Image: see text] Herein, we report on one-dimensional porous Au-modified LaFeO(3) nanobelts (NBs) with high surface area, which were synthesized through the electrospinning method. The incorporation and coverage of Au nanoparticles (NPs) on the surface of the LaFeO(3) NBs was achieved by adjusting...

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Autores principales: Shingange, Katekani, Swart, Hendrik, Mhlongo, Gugu H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6868597/
https://www.ncbi.nlm.nih.gov/pubmed/31763524
http://dx.doi.org/10.1021/acsomega.9b01989
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author Shingange, Katekani
Swart, Hendrik
Mhlongo, Gugu H.
author_facet Shingange, Katekani
Swart, Hendrik
Mhlongo, Gugu H.
author_sort Shingange, Katekani
collection PubMed
description [Image: see text] Herein, we report on one-dimensional porous Au-modified LaFeO(3) nanobelts (NBs) with high surface area, which were synthesized through the electrospinning method. The incorporation and coverage of Au nanoparticles (NPs) on the surface of the LaFeO(3) NBs was achieved by adjusting the HAuCl amount in the precursor solution. Successful incorporation of Au NPs was examined by X-ray diffraction, high-resolution transmission electron microscopy, and X-ray photoelectron spectroscopy. The gas-sensing performance of both the pure and Au/LaFeO(3) NB-based sensors was tested toward 2.5–40 ppm of acetone at working temperatures in the range from room temperature to 180 °C. The gas-sensing findings revealed that Au/LaFeO(3) NB-based sensor with the Au concentration of 0.3 wt % displayed improved response of 125–40 ppm of acetone and rapid response and recovery times of 26 and 20 s, respectively, at an optimal working temperature of 100 °C. Furthermore, all sensors demonstrated an excellent response toward acetone and remarkable selectivity against NO(2), NH(3), CH(4), and CO. Hence, the Au/LaFeO(3)-NB-based sensor is a promising candidate for sensitive, ultrafast, and selective acetone detections at low concentrations. The gas-sensing mechanism of the Au/LaFeO(3) sensors is explained in consideration of the catalytic activity of the Au NPs, which served as direct adsorption sites for oxygen and acetone.
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spelling pubmed-68685972019-11-22 Ultrafast Detection of Low Acetone Concentration Displayed by Au-Loaded LaFeO(3) Nanobelts owing to Synergetic Effects of Porous 1D Morphology and Catalytic Activity of Au Nanoparticles Shingange, Katekani Swart, Hendrik Mhlongo, Gugu H. ACS Omega [Image: see text] Herein, we report on one-dimensional porous Au-modified LaFeO(3) nanobelts (NBs) with high surface area, which were synthesized through the electrospinning method. The incorporation and coverage of Au nanoparticles (NPs) on the surface of the LaFeO(3) NBs was achieved by adjusting the HAuCl amount in the precursor solution. Successful incorporation of Au NPs was examined by X-ray diffraction, high-resolution transmission electron microscopy, and X-ray photoelectron spectroscopy. The gas-sensing performance of both the pure and Au/LaFeO(3) NB-based sensors was tested toward 2.5–40 ppm of acetone at working temperatures in the range from room temperature to 180 °C. The gas-sensing findings revealed that Au/LaFeO(3) NB-based sensor with the Au concentration of 0.3 wt % displayed improved response of 125–40 ppm of acetone and rapid response and recovery times of 26 and 20 s, respectively, at an optimal working temperature of 100 °C. Furthermore, all sensors demonstrated an excellent response toward acetone and remarkable selectivity against NO(2), NH(3), CH(4), and CO. Hence, the Au/LaFeO(3)-NB-based sensor is a promising candidate for sensitive, ultrafast, and selective acetone detections at low concentrations. The gas-sensing mechanism of the Au/LaFeO(3) sensors is explained in consideration of the catalytic activity of the Au NPs, which served as direct adsorption sites for oxygen and acetone. American Chemical Society 2019-11-05 /pmc/articles/PMC6868597/ /pubmed/31763524 http://dx.doi.org/10.1021/acsomega.9b01989 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Shingange, Katekani
Swart, Hendrik
Mhlongo, Gugu H.
Ultrafast Detection of Low Acetone Concentration Displayed by Au-Loaded LaFeO(3) Nanobelts owing to Synergetic Effects of Porous 1D Morphology and Catalytic Activity of Au Nanoparticles
title Ultrafast Detection of Low Acetone Concentration Displayed by Au-Loaded LaFeO(3) Nanobelts owing to Synergetic Effects of Porous 1D Morphology and Catalytic Activity of Au Nanoparticles
title_full Ultrafast Detection of Low Acetone Concentration Displayed by Au-Loaded LaFeO(3) Nanobelts owing to Synergetic Effects of Porous 1D Morphology and Catalytic Activity of Au Nanoparticles
title_fullStr Ultrafast Detection of Low Acetone Concentration Displayed by Au-Loaded LaFeO(3) Nanobelts owing to Synergetic Effects of Porous 1D Morphology and Catalytic Activity of Au Nanoparticles
title_full_unstemmed Ultrafast Detection of Low Acetone Concentration Displayed by Au-Loaded LaFeO(3) Nanobelts owing to Synergetic Effects of Porous 1D Morphology and Catalytic Activity of Au Nanoparticles
title_short Ultrafast Detection of Low Acetone Concentration Displayed by Au-Loaded LaFeO(3) Nanobelts owing to Synergetic Effects of Porous 1D Morphology and Catalytic Activity of Au Nanoparticles
title_sort ultrafast detection of low acetone concentration displayed by au-loaded lafeo(3) nanobelts owing to synergetic effects of porous 1d morphology and catalytic activity of au nanoparticles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6868597/
https://www.ncbi.nlm.nih.gov/pubmed/31763524
http://dx.doi.org/10.1021/acsomega.9b01989
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