Halloysite-Catalyzed Esterification of Bio-Mass Derived Acids

[Image: see text] Halloysite, a natural clay with a hollow tubular structure, was studied as a catalyst for the esterification of biomass-derived carboxylic acids (levulinic acid, fumaric acid, maleic acid, and succinic acid) with four different alcohols (MeOH, EtOH, n-PrOH, and n-BuOH). Reaction co...

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Autores principales: Hamdi, Jumanah, Diehl, Brooke N., Kilgore, Kaylin, Lomenzo, Stacey A, Trudell, Mark L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6868903/
https://www.ncbi.nlm.nih.gov/pubmed/31763567
http://dx.doi.org/10.1021/acsomega.9b02870
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author Hamdi, Jumanah
Diehl, Brooke N.
Kilgore, Kaylin
Lomenzo, Stacey A
Trudell, Mark L.
author_facet Hamdi, Jumanah
Diehl, Brooke N.
Kilgore, Kaylin
Lomenzo, Stacey A
Trudell, Mark L.
author_sort Hamdi, Jumanah
collection PubMed
description [Image: see text] Halloysite, a natural clay with a hollow tubular structure, was studied as a catalyst for the esterification of biomass-derived carboxylic acids (levulinic acid, fumaric acid, maleic acid, and succinic acid) with four different alcohols (MeOH, EtOH, n-PrOH, and n-BuOH). Reaction conditions were optimized (10 mol % halloysite, 170 °C, 24 h) and gave high yields of the corresponding esters and diesters (>90%). The halloysite was easily recovered and recycled after washing and drying.
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spelling pubmed-68689032019-11-22 Halloysite-Catalyzed Esterification of Bio-Mass Derived Acids Hamdi, Jumanah Diehl, Brooke N. Kilgore, Kaylin Lomenzo, Stacey A Trudell, Mark L. ACS Omega [Image: see text] Halloysite, a natural clay with a hollow tubular structure, was studied as a catalyst for the esterification of biomass-derived carboxylic acids (levulinic acid, fumaric acid, maleic acid, and succinic acid) with four different alcohols (MeOH, EtOH, n-PrOH, and n-BuOH). Reaction conditions were optimized (10 mol % halloysite, 170 °C, 24 h) and gave high yields of the corresponding esters and diesters (>90%). The halloysite was easily recovered and recycled after washing and drying. American Chemical Society 2019-11-05 /pmc/articles/PMC6868903/ /pubmed/31763567 http://dx.doi.org/10.1021/acsomega.9b02870 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Hamdi, Jumanah
Diehl, Brooke N.
Kilgore, Kaylin
Lomenzo, Stacey A
Trudell, Mark L.
Halloysite-Catalyzed Esterification of Bio-Mass Derived Acids
title Halloysite-Catalyzed Esterification of Bio-Mass Derived Acids
title_full Halloysite-Catalyzed Esterification of Bio-Mass Derived Acids
title_fullStr Halloysite-Catalyzed Esterification of Bio-Mass Derived Acids
title_full_unstemmed Halloysite-Catalyzed Esterification of Bio-Mass Derived Acids
title_short Halloysite-Catalyzed Esterification of Bio-Mass Derived Acids
title_sort halloysite-catalyzed esterification of bio-mass derived acids
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6868903/
https://www.ncbi.nlm.nih.gov/pubmed/31763567
http://dx.doi.org/10.1021/acsomega.9b02870
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