Cargando…

Room-Temperature Asymmetric Transfer Hydrogenation of Biomass-Derived Levulinic Acid to Optically Pure γ-Valerolactone Using a Ruthenium Catalyst

[Image: see text] This study presents a first report on ruthenium-catalyzed asymmetric transfer hydrogenation (ATH) of levulinic acid (LA) to chiral γ-valerolactone (GVL). ATH of LA has been explored with Noyori’s chiral catalyst (Ru–TsDPEN) in methanol solvent. Efficacy of ATH reaction of LA was in...

Descripción completa

Detalles Bibliográficos
Autores principales:	Shende, Vaishali S., Raut, Amol B., Raghav, Prathamesh, Kelkar, Ashutosh A., Bhanage, Bhalchandra M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2019
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6868911/ https://www.ncbi.nlm.nih.gov/pubmed/31763574 http://dx.doi.org/10.1021/acsomega.9b03424

Ejemplares similares

Highly Enantioselective One-Pot Synthesis of Chiral β-Heterosubstituted Alcohols via Ruthenium–Prolinamide-Catalyzed Asymmetric Transfer Hydrogenation
por: Vyas, Vijyesh K., et al.
Publicado: (2018)

Influence of Sulfuric Acid on the Performance of Ruthenium‐based Catalysts in the Liquid‐Phase Hydrogenation of Levulinic Acid to γ‐Valerolactone
por: Ftouni, Jamal, et al.
Publicado: (2017)

Reductive Upgrading of Biomass-Based Levulinic Acid to γ-Valerolactone Over Ru-Based Single-Atom Catalysts
por: Meng, Ye, et al.
Publicado: (2022)

Polymeric Ruthenium Porphyrin-Functionalized Carbon Nanotubes and Graphene for Levulinic Ester Transformations into γ-Valerolactone and Pyrrolidone Derivatives
por: Zhang, Ting, et al.
Publicado: (2017)

Nanostructured Nickel/Silica Catalysts for Continuous Flow Conversion of Levulinic Acid to γ-Valerolactone
por: Mallesham, Baithy, et al.
Publicado: (2018)

Ru@hyperbranched Polymer for Hydrogenation of Levulinic Acid to Gamma-Valerolactone: The Role of the Catalyst Support
por: Sorokina, Svetlana A., et al.
Publicado: (2022)

Robust Ruthenium Catalysts Supported on Mesoporous Cyclodextrin-Templated TiO(2)-SiO(2) Mixed Oxides for the Hydrogenation of Levulinic Acid to γ-Valerolactone
por: Decarpigny, Cédric, et al.
Publicado: (2021)

Synergistic Catalysis of Ruthenium Nanoparticles and Polyoxometalate Integrated Within Single UiO−66 Microcrystals for Boosting the Efficiency of Methyl Levulinate to γ-Valerolactone
por: Cai, Xiaoxiong, et al.
Publicado: (2019)

Hydrodeoxygenation of Levulinic Acid to γ-Valerolactone over Mesoporous Silica-Supported Cu-Ni Composite Catalysts
por: Popova, Margarita, et al.
Publicado: (2022)

Catalytic valorisation of biomass levulinic acid into gamma valerolactone using formic acid as a H(2) donor: a critical review
por: Hijazi, Ayman, et al.
Publicado: (2022)

Vapor-Phase Hydrogenation of Levulinic Acid to γ-Valerolactone Over Bi-Functional Ni/HZSM-5 Catalyst
por: Popova, Margarita, et al.
Publicado: (2018)

Continuous flow hydrogenation of methyl and ethyl levulinate: an alternative route to γ-valerolactone production
por: Tukacs, József M., et al.
Publicado: (2019)

Modeling and Thermodynamic Studies of γ‐Valerolactone Production from Bio‐derived Methyl Levulinate
por: Montejano‐Nares, Elena, et al.
Publicado: (2023)

Efficient Vapor‐Phase Selective Hydrogenolysis of Bio‐Levulinic Acid to γ‐Valerolactone Using Cu Supported on Hydrotalcite Catalysts
por: Mitta, Harisekhar, et al.
Publicado: (2018)

High performing and stable supported nano-alloys for the catalytic hydrogenation of levulinic acid to γ-valerolactone
por: Luo, Wenhao, et al.
Publicado: (2015)

Silylated Zeolites With Enhanced Hydrothermal Stability for the Aqueous-Phase Hydrogenation of Levulinic Acid to γ-Valerolactone
por: Vu, Hue-Tong, et al.
Publicado: (2018)

Porous Ti/Zr Microspheres for Efficient Transfer Hydrogenation of Biobased Ethyl Levulinate to γ-Valerolactone
por: Yang, Tingting, et al.
Publicado: (2017)

Recent Advances in Ruthenium-Catalyzed Hydrogenation Reactions of Renewable Biomass-Derived Levulinic Acid in Aqueous Media
por: Seretis, Aristeidis, et al.
Publicado: (2020)

Easy Method for the Transformation of Levulinic Acid into Gamma-Valerolactone Using a Nickel Catalyst Derived from Nanocasted Nickel Oxide
por: Sanchis, Rut, et al.
Publicado: (2019)

Highly efficient selective hydrogenation of levulinic acid to γ-valerolactone over Cu–Re/TiO(2) bimetallic catalysts
por: Liu, Yingxin, et al.
Publicado: (2021)

Computational Mechanism of Methyl Levulinate Conversion to γ-Valerolactone on UiO-66 Metal Organic Frameworks
por: Ortuño, Manuel A., et al.
Publicado: (2022)

Low temperature conversion of levulinic acid into γ-valerolactone using Zn to generate hydrogen from water and nickel catalysts supported on sepiolite
por: García, Adrián, et al.
Publicado: (2020)

Surface engineering in PbS via partial oxidation: towards an advanced electrocatalyst for reduction of levulinic acid to γ-valerolactone
por: Wu, Haoran, et al.
Publicado: (2018)

Conversion of levulinic acid to γ-valerolactone over Ru/Al(2)O(3)–TiO(2) catalyst under mild conditions
por: Wang, Ruifeng, et al.
Publicado: (2018)

Enhancing the conversion of ethyl levulinate to γ-valerolactone over Ru/UiO-66 by introducing sulfonic groups into the framework
por: Yang, Jie, et al.
Publicado: (2018)

Continuous hydrogenation of ethyl levulinate to γ-valerolactone and 2-methyl tetrahydrofuran over alumina doped Cu/SiO(2) catalyst: the potential of commercialization
por: Zheng, Junlin, et al.
Publicado: (2016)

Cascade Upgrading of Biomass-Derived Furfural to γ-Valerolactone Over Zr/Hf-Based Catalysts
por: Sun, Wenjuan, et al.
Publicado: (2022)

Probing the mechanism of the conversion of methyl levulinate into γ-valerolactone catalyzed by Al(OiPr)(3) in an alcohol solvent: a DFT study
por: Ju, Zhaoyang, et al.
Publicado: (2022)

Electrodeposited Ni-Rich Ni–Pt Mesoporous Nanowires for Selective and Efficient Formic Acid-Assisted Hydrogenation of Levulinic Acid to γ-Valerolactone
por: Serrà, Albert, et al.
Publicado: (2021)

γ-Valerolactone Production from Levulinic Acid Hydrogenation Using Ni Supported Nanoparticles: Influence of Tungsten Loading and pH of Synthesis
por: Córdova-Pérez, Gerardo E., et al.
Publicado: (2022)

Catalytic Production of Levulinic Acid (LA) from Actual Biomass
por: Signoretto, Michela, et al.
Publicado: (2019)

Current Approaches to Alkyl Levulinates via Efficient Valorization of Biomass Derivatives
por: Liu, Xiaofang, et al.
Publicado: (2020)

Recovery of yttrium and europium from spent fluorescent lamps using pure levulinic acid and the deep eutectic solvent levulinic acid–choline chloride
por: Pateli, Ioanna M., et al.
Publicado: (2020)

Microwave-Assisted γ-Valerolactone Production for Biomass Lignin Extraction: A Cascade Protocol
por: Tabasso, Silvia, et al.
Publicado: (2016)

Levulinic acid
por: Hachuła, Barbara, et al.
Publicado: (2013)

A Novel Tannic Acid-Based Carbon-Supported Cobalt Catalyst for Transfer Hydrogenation of Biomass Derived Ethyl Levulinate
por: Wang, Meng, et al.
Publicado: (2022)

Alkyl Levulinates and 2-Methyltetrahydrofuran: Possible Biomass-Based Solvents in Palladium-Catalyzed Aminocarbonylation
por: Uzunlu, Nuray, et al.
Publicado: (2023)

Influence of Levulinic Acid Hydrogenation on Aluminum Coordination in Zeolite‐Supported Ruthenium Catalysts: A (27)Al 3QMAS Nuclear Magnetic Resonance Study
por: Luo, Wenhao, et al.
Publicado: (2017)

Acetoxy-γ-valerolactone
por: Tristram, Cameron, et al.
Publicado: (2013)

Synthesis of Ethylene Glycol from Syngas via Oxidative Double Carbonylation of Ethanol to Diethyl Oxalate and Its Subsequent Hydrogenation
por: Satapathy, Anilkumar, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_1asnqk8htf84hdrajlm96k421l