Cargando…
The Synthesis and Utility of Metal-Nitrosophenolato Compounds—Highlighting the Baudisch Reaction
The syntheses of the title compounds demonstrate a privileged introduction of a nitroso (and a hydroxyl via the Baudisch reaction) group to an aromatic ring. These complexes first appeared in the literature as early as 1939, and a range of applications has subsequently been published. However, optim...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6891451/ https://www.ncbi.nlm.nih.gov/pubmed/31698829 http://dx.doi.org/10.3390/molecules24224018 |
_version_ | 1783475817065480192 |
---|---|
author | Nicholls, Alexander J. Barber, Thomas Baxendale, Ian R. |
author_facet | Nicholls, Alexander J. Barber, Thomas Baxendale, Ian R. |
author_sort | Nicholls, Alexander J. |
collection | PubMed |
description | The syntheses of the title compounds demonstrate a privileged introduction of a nitroso (and a hydroxyl via the Baudisch reaction) group to an aromatic ring. These complexes first appeared in the literature as early as 1939, and a range of applications has subsequently been published. However, optimisations of the preparative sequences were not considered, and as such, the reactions have seldom been utilised in recent years; indeed, there remains confusion in the literature as to how such complexes form. In this review, we aim to demystify the misunderstanding surrounding these remarkable complexes and consider their renewed application in the 21st century. |
format | Online Article Text |
id | pubmed-6891451 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-68914512019-12-18 The Synthesis and Utility of Metal-Nitrosophenolato Compounds—Highlighting the Baudisch Reaction Nicholls, Alexander J. Barber, Thomas Baxendale, Ian R. Molecules Review The syntheses of the title compounds demonstrate a privileged introduction of a nitroso (and a hydroxyl via the Baudisch reaction) group to an aromatic ring. These complexes first appeared in the literature as early as 1939, and a range of applications has subsequently been published. However, optimisations of the preparative sequences were not considered, and as such, the reactions have seldom been utilised in recent years; indeed, there remains confusion in the literature as to how such complexes form. In this review, we aim to demystify the misunderstanding surrounding these remarkable complexes and consider their renewed application in the 21st century. MDPI 2019-11-06 /pmc/articles/PMC6891451/ /pubmed/31698829 http://dx.doi.org/10.3390/molecules24224018 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Review Nicholls, Alexander J. Barber, Thomas Baxendale, Ian R. The Synthesis and Utility of Metal-Nitrosophenolato Compounds—Highlighting the Baudisch Reaction |
title | The Synthesis and Utility of Metal-Nitrosophenolato Compounds—Highlighting the Baudisch Reaction |
title_full | The Synthesis and Utility of Metal-Nitrosophenolato Compounds—Highlighting the Baudisch Reaction |
title_fullStr | The Synthesis and Utility of Metal-Nitrosophenolato Compounds—Highlighting the Baudisch Reaction |
title_full_unstemmed | The Synthesis and Utility of Metal-Nitrosophenolato Compounds—Highlighting the Baudisch Reaction |
title_short | The Synthesis and Utility of Metal-Nitrosophenolato Compounds—Highlighting the Baudisch Reaction |
title_sort | synthesis and utility of metal-nitrosophenolato compounds—highlighting the baudisch reaction |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6891451/ https://www.ncbi.nlm.nih.gov/pubmed/31698829 http://dx.doi.org/10.3390/molecules24224018 |
work_keys_str_mv | AT nichollsalexanderj thesynthesisandutilityofmetalnitrosophenolatocompoundshighlightingthebaudischreaction AT barberthomas thesynthesisandutilityofmetalnitrosophenolatocompoundshighlightingthebaudischreaction AT baxendaleianr thesynthesisandutilityofmetalnitrosophenolatocompoundshighlightingthebaudischreaction AT nichollsalexanderj synthesisandutilityofmetalnitrosophenolatocompoundshighlightingthebaudischreaction AT barberthomas synthesisandutilityofmetalnitrosophenolatocompoundshighlightingthebaudischreaction AT baxendaleianr synthesisandutilityofmetalnitrosophenolatocompoundshighlightingthebaudischreaction |