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Calcium Valence-to-Core X-ray Emission Spectroscopy: A Sensitive Probe of Oxo Protonation in Structural Models of the Oxygen-Evolving Complex

[Image: see text] Calcium is an abundant, nontoxic metal that finds many roles in synthetic and biological systems including the oxygen-evolving complex (OEC) of photosystem II. Characterization methods for calcium centers, however, are underdeveloped compared to those available for transition metal...

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Detalles Bibliográficos
Autores principales:	Mathe, Zachary, Pantazis, Dimitrios A., Lee, Heui Beom, Gnewkow, Richard, Van Kuiken, Benjamin E., Agapie, Theodor, DeBeer, Serena
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2019
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6891804/ https://www.ncbi.nlm.nih.gov/pubmed/31743026 http://dx.doi.org/10.1021/acs.inorgchem.9b02866

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