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Temperature-Controlled Synthesis of Li- and Mn-Rich Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) Hollow Nano/Sub-Microsphere Electrodes for High-Performance Lithium-Ion Battery

[Image: see text] The calcination temperature plays a significant role in the structural, textural, and energy-storage performance of metal oxide nanomaterials in Li-ion battery application. Here, we report the formation of well-crystallized homogeneously dispersed Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2...

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Autores principales: Alagar, Srinivasan, Karuppiah, Chelladurai, Madhuvilakku, Rajesh, Piraman, Shakkthivel, Yang, Chun-Chen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6893958/
https://www.ncbi.nlm.nih.gov/pubmed/31815231
http://dx.doi.org/10.1021/acsomega.9b02766
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author Alagar, Srinivasan
Karuppiah, Chelladurai
Madhuvilakku, Rajesh
Piraman, Shakkthivel
Yang, Chun-Chen
author_facet Alagar, Srinivasan
Karuppiah, Chelladurai
Madhuvilakku, Rajesh
Piraman, Shakkthivel
Yang, Chun-Chen
author_sort Alagar, Srinivasan
collection PubMed
description [Image: see text] The calcination temperature plays a significant role in the structural, textural, and energy-storage performance of metal oxide nanomaterials in Li-ion battery application. Here, we report the formation of well-crystallized homogeneously dispersed Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) hollow nano/sub-microsphere architectures through a simple cost-effective coprecipitation and chemical mixing route without surface modification for improving the efficiency of energy storage devices. The synthesized Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) hollow nano/sub-microsphere cathode materials are calcined at 800, 900, 950, and 1000 °C. Among them, Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) calcined at 950 °C exhibits a high discharge capacity (277 mAh g(–1) at 0.1C rate) and excellent capacity retention (88%) after 50 cycles and also delivers an excellent discharge capacity of >172 mAh g(–1) at 5C rate. Good electrochemical performance of Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2)-950 is directly related to the optimized size of its primary particles (85 nm) (which constitute the spherical secondary particle, ∼720 nm) and homogeneous cation mixing. Higher calcination temperature (≥950 °C) leads to an increase of the primary particle size, poor cycling stability, and inferior rate capacity of Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) due to smashing of quasi-hollow spheres upon repeated lithium ion intercalations/deintercalations. Therefore, Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2)-950 is a promising electrode for the next-generation high-voltage and high-capacity Li-ion battery application.
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spelling pubmed-68939582019-12-06 Temperature-Controlled Synthesis of Li- and Mn-Rich Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) Hollow Nano/Sub-Microsphere Electrodes for High-Performance Lithium-Ion Battery Alagar, Srinivasan Karuppiah, Chelladurai Madhuvilakku, Rajesh Piraman, Shakkthivel Yang, Chun-Chen ACS Omega [Image: see text] The calcination temperature plays a significant role in the structural, textural, and energy-storage performance of metal oxide nanomaterials in Li-ion battery application. Here, we report the formation of well-crystallized homogeneously dispersed Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) hollow nano/sub-microsphere architectures through a simple cost-effective coprecipitation and chemical mixing route without surface modification for improving the efficiency of energy storage devices. The synthesized Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) hollow nano/sub-microsphere cathode materials are calcined at 800, 900, 950, and 1000 °C. Among them, Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) calcined at 950 °C exhibits a high discharge capacity (277 mAh g(–1) at 0.1C rate) and excellent capacity retention (88%) after 50 cycles and also delivers an excellent discharge capacity of >172 mAh g(–1) at 5C rate. Good electrochemical performance of Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2)-950 is directly related to the optimized size of its primary particles (85 nm) (which constitute the spherical secondary particle, ∼720 nm) and homogeneous cation mixing. Higher calcination temperature (≥950 °C) leads to an increase of the primary particle size, poor cycling stability, and inferior rate capacity of Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) due to smashing of quasi-hollow spheres upon repeated lithium ion intercalations/deintercalations. Therefore, Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2)-950 is a promising electrode for the next-generation high-voltage and high-capacity Li-ion battery application. American Chemical Society 2019-11-21 /pmc/articles/PMC6893958/ /pubmed/31815231 http://dx.doi.org/10.1021/acsomega.9b02766 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Alagar, Srinivasan
Karuppiah, Chelladurai
Madhuvilakku, Rajesh
Piraman, Shakkthivel
Yang, Chun-Chen
Temperature-Controlled Synthesis of Li- and Mn-Rich Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) Hollow Nano/Sub-Microsphere Electrodes for High-Performance Lithium-Ion Battery
title Temperature-Controlled Synthesis of Li- and Mn-Rich Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) Hollow Nano/Sub-Microsphere Electrodes for High-Performance Lithium-Ion Battery
title_full Temperature-Controlled Synthesis of Li- and Mn-Rich Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) Hollow Nano/Sub-Microsphere Electrodes for High-Performance Lithium-Ion Battery
title_fullStr Temperature-Controlled Synthesis of Li- and Mn-Rich Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) Hollow Nano/Sub-Microsphere Electrodes for High-Performance Lithium-Ion Battery
title_full_unstemmed Temperature-Controlled Synthesis of Li- and Mn-Rich Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) Hollow Nano/Sub-Microsphere Electrodes for High-Performance Lithium-Ion Battery
title_short Temperature-Controlled Synthesis of Li- and Mn-Rich Li(1.2)Mn(0.54)Ni(0.13)Co(0.13)O(2) Hollow Nano/Sub-Microsphere Electrodes for High-Performance Lithium-Ion Battery
title_sort temperature-controlled synthesis of li- and mn-rich li(1.2)mn(0.54)ni(0.13)co(0.13)o(2) hollow nano/sub-microsphere electrodes for high-performance lithium-ion battery
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6893958/
https://www.ncbi.nlm.nih.gov/pubmed/31815231
http://dx.doi.org/10.1021/acsomega.9b02766
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