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Iodine-Catalyzed Functionalization of Primary Aliphatic Amines to Oxazoles, 1,4-Oxazines, and Oxazinones

[Image: see text] Unprecedented I(2)-catalyzed α,α-C(sp(3))-H, decarboxylative α-C(sp(3))-H, lactonized α-C(sp(3))-H, and α,β-C(sp(3))-H functionalized 5- and 6-annulation as well as α-C(sp(3))-H activated 6-lactonization of primary aliphatic amines are devised under aerobic conditions. The metal-fr...

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Detalles Bibliográficos
Autores principales: Debnath, Sudipto, Das, Tuluma, Gayen, Subrata, Ghosh, Tapas, Maiti, Dilip K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6894181/
https://www.ncbi.nlm.nih.gov/pubmed/31815245
http://dx.doi.org/10.1021/acsomega.9b03501

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