Deoxydehydration of vicinal diols by homogeneous catalysts: a mechanistic overview

Deoxydehydration (DODH) is an important reaction for the upconversion of biomass-derived polyols to commodity chemicals such as alkenes and dienes. DODH can be performed by a variety of early metal-oxo catalysts incorporating Re, Mo and V. The varying reduction methods used in the DODH catalytic cyc...

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Detalles Bibliográficos
Autores principales: DeNike, Kayla A., Kilyanek, Stefan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6894556/
https://www.ncbi.nlm.nih.gov/pubmed/31827851
http://dx.doi.org/10.1098/rsos.191165
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author DeNike, Kayla A.
Kilyanek, Stefan M.
author_facet DeNike, Kayla A.
Kilyanek, Stefan M.
author_sort DeNike, Kayla A.
collection PubMed
description Deoxydehydration (DODH) is an important reaction for the upconversion of biomass-derived polyols to commodity chemicals such as alkenes and dienes. DODH can be performed by a variety of early metal-oxo catalysts incorporating Re, Mo and V. The varying reduction methods used in the DODH catalytic cycle impact the product distribution, reaction mechanism and the overall yield of the reaction. This review surveys the reduction methods commonly used in homogeneous DODH catalyst systems and their impacts on yield and reaction conditions.
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spelling pubmed-68945562019-12-11 Deoxydehydration of vicinal diols by homogeneous catalysts: a mechanistic overview DeNike, Kayla A. Kilyanek, Stefan M. R Soc Open Sci Chemistry Deoxydehydration (DODH) is an important reaction for the upconversion of biomass-derived polyols to commodity chemicals such as alkenes and dienes. DODH can be performed by a variety of early metal-oxo catalysts incorporating Re, Mo and V. The varying reduction methods used in the DODH catalytic cycle impact the product distribution, reaction mechanism and the overall yield of the reaction. This review surveys the reduction methods commonly used in homogeneous DODH catalyst systems and their impacts on yield and reaction conditions. The Royal Society 2019-11-06 /pmc/articles/PMC6894556/ /pubmed/31827851 http://dx.doi.org/10.1098/rsos.191165 Text en © 2019 The Authors. http://creativecommons.org/licenses/by/4.0/ Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/, which permits unrestricted use, provided the original author and source are credited.
spellingShingle Chemistry
DeNike, Kayla A.
Kilyanek, Stefan M.
Deoxydehydration of vicinal diols by homogeneous catalysts: a mechanistic overview
title Deoxydehydration of vicinal diols by homogeneous catalysts: a mechanistic overview
title_full Deoxydehydration of vicinal diols by homogeneous catalysts: a mechanistic overview
title_fullStr Deoxydehydration of vicinal diols by homogeneous catalysts: a mechanistic overview
title_full_unstemmed Deoxydehydration of vicinal diols by homogeneous catalysts: a mechanistic overview
title_short Deoxydehydration of vicinal diols by homogeneous catalysts: a mechanistic overview
title_sort deoxydehydration of vicinal diols by homogeneous catalysts: a mechanistic overview
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6894556/
https://www.ncbi.nlm.nih.gov/pubmed/31827851
http://dx.doi.org/10.1098/rsos.191165
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