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Methods for the reaction of alkenes with activated tungstic acid
In this study, we have synthesized activated tungstic acid by dehydration of tungstic acid as a highly efficient catalyst and employed it for the catalytic transformations of various alkenes. The importance of this series of studies is to help students to graphically visualize a diverse array of org...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895725/ https://www.ncbi.nlm.nih.gov/pubmed/31844714 http://dx.doi.org/10.1016/j.heliyon.2019.e02780 |
Sumario: | In this study, we have synthesized activated tungstic acid by dehydration of tungstic acid as a highly efficient catalyst and employed it for the catalytic transformations of various alkenes. The importance of this series of studies is to help students to graphically visualize a diverse array of organic synthesis reactions. The alkenes react differently depending on their structure via mainly acid-catalyzed reactions that produce a whole range of products including coupled products (dimers). For example, Cyclopentene was transformed into 1,1′-bi (cyclopent-3-ene) in yield 100% at room temperature. Cyclohexene-3-cyclohexyl was form from Cyclohexene. The synthesized product was identified and confirmed by gas chromatography and mass spectroscopy, measuring the retention times of authentic samples of the compounds. |
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