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Methods for the reaction of alkenes with activated tungstic acid

In this study, we have synthesized activated tungstic acid by dehydration of tungstic acid as a highly efficient catalyst and employed it for the catalytic transformations of various alkenes. The importance of this series of studies is to help students to graphically visualize a diverse array of org...

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Detalles Bibliográficos
Autores principales: Alrefaee, Salhah Hamed, Apblett, Allen W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895725/
https://www.ncbi.nlm.nih.gov/pubmed/31844714
http://dx.doi.org/10.1016/j.heliyon.2019.e02780
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author Alrefaee, Salhah Hamed
Apblett, Allen W.
author_facet Alrefaee, Salhah Hamed
Apblett, Allen W.
author_sort Alrefaee, Salhah Hamed
collection PubMed
description In this study, we have synthesized activated tungstic acid by dehydration of tungstic acid as a highly efficient catalyst and employed it for the catalytic transformations of various alkenes. The importance of this series of studies is to help students to graphically visualize a diverse array of organic synthesis reactions. The alkenes react differently depending on their structure via mainly acid-catalyzed reactions that produce a whole range of products including coupled products (dimers). For example, Cyclopentene was transformed into 1,1′-bi (cyclopent-3-ene) in yield 100% at room temperature. Cyclohexene-3-cyclohexyl was form from Cyclohexene. The synthesized product was identified and confirmed by gas chromatography and mass spectroscopy, measuring the retention times of authentic samples of the compounds.
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spelling pubmed-68957252019-12-16 Methods for the reaction of alkenes with activated tungstic acid Alrefaee, Salhah Hamed Apblett, Allen W. Heliyon Article In this study, we have synthesized activated tungstic acid by dehydration of tungstic acid as a highly efficient catalyst and employed it for the catalytic transformations of various alkenes. The importance of this series of studies is to help students to graphically visualize a diverse array of organic synthesis reactions. The alkenes react differently depending on their structure via mainly acid-catalyzed reactions that produce a whole range of products including coupled products (dimers). For example, Cyclopentene was transformed into 1,1′-bi (cyclopent-3-ene) in yield 100% at room temperature. Cyclohexene-3-cyclohexyl was form from Cyclohexene. The synthesized product was identified and confirmed by gas chromatography and mass spectroscopy, measuring the retention times of authentic samples of the compounds. Elsevier 2019-11-21 /pmc/articles/PMC6895725/ /pubmed/31844714 http://dx.doi.org/10.1016/j.heliyon.2019.e02780 Text en © 2019 The Author(s) http://creativecommons.org/licenses/by-nc-nd/4.0/ This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Article
Alrefaee, Salhah Hamed
Apblett, Allen W.
Methods for the reaction of alkenes with activated tungstic acid
title Methods for the reaction of alkenes with activated tungstic acid
title_full Methods for the reaction of alkenes with activated tungstic acid
title_fullStr Methods for the reaction of alkenes with activated tungstic acid
title_full_unstemmed Methods for the reaction of alkenes with activated tungstic acid
title_short Methods for the reaction of alkenes with activated tungstic acid
title_sort methods for the reaction of alkenes with activated tungstic acid
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895725/
https://www.ncbi.nlm.nih.gov/pubmed/31844714
http://dx.doi.org/10.1016/j.heliyon.2019.e02780
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