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Methods for the reaction of alkenes with activated tungstic acid
In this study, we have synthesized activated tungstic acid by dehydration of tungstic acid as a highly efficient catalyst and employed it for the catalytic transformations of various alkenes. The importance of this series of studies is to help students to graphically visualize a diverse array of org...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895725/ https://www.ncbi.nlm.nih.gov/pubmed/31844714 http://dx.doi.org/10.1016/j.heliyon.2019.e02780 |
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author | Alrefaee, Salhah Hamed Apblett, Allen W. |
author_facet | Alrefaee, Salhah Hamed Apblett, Allen W. |
author_sort | Alrefaee, Salhah Hamed |
collection | PubMed |
description | In this study, we have synthesized activated tungstic acid by dehydration of tungstic acid as a highly efficient catalyst and employed it for the catalytic transformations of various alkenes. The importance of this series of studies is to help students to graphically visualize a diverse array of organic synthesis reactions. The alkenes react differently depending on their structure via mainly acid-catalyzed reactions that produce a whole range of products including coupled products (dimers). For example, Cyclopentene was transformed into 1,1′-bi (cyclopent-3-ene) in yield 100% at room temperature. Cyclohexene-3-cyclohexyl was form from Cyclohexene. The synthesized product was identified and confirmed by gas chromatography and mass spectroscopy, measuring the retention times of authentic samples of the compounds. |
format | Online Article Text |
id | pubmed-6895725 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | Elsevier |
record_format | MEDLINE/PubMed |
spelling | pubmed-68957252019-12-16 Methods for the reaction of alkenes with activated tungstic acid Alrefaee, Salhah Hamed Apblett, Allen W. Heliyon Article In this study, we have synthesized activated tungstic acid by dehydration of tungstic acid as a highly efficient catalyst and employed it for the catalytic transformations of various alkenes. The importance of this series of studies is to help students to graphically visualize a diverse array of organic synthesis reactions. The alkenes react differently depending on their structure via mainly acid-catalyzed reactions that produce a whole range of products including coupled products (dimers). For example, Cyclopentene was transformed into 1,1′-bi (cyclopent-3-ene) in yield 100% at room temperature. Cyclohexene-3-cyclohexyl was form from Cyclohexene. The synthesized product was identified and confirmed by gas chromatography and mass spectroscopy, measuring the retention times of authentic samples of the compounds. Elsevier 2019-11-21 /pmc/articles/PMC6895725/ /pubmed/31844714 http://dx.doi.org/10.1016/j.heliyon.2019.e02780 Text en © 2019 The Author(s) http://creativecommons.org/licenses/by-nc-nd/4.0/ This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Article Alrefaee, Salhah Hamed Apblett, Allen W. Methods for the reaction of alkenes with activated tungstic acid |
title | Methods for the reaction of alkenes with activated tungstic acid |
title_full | Methods for the reaction of alkenes with activated tungstic acid |
title_fullStr | Methods for the reaction of alkenes with activated tungstic acid |
title_full_unstemmed | Methods for the reaction of alkenes with activated tungstic acid |
title_short | Methods for the reaction of alkenes with activated tungstic acid |
title_sort | methods for the reaction of alkenes with activated tungstic acid |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895725/ https://www.ncbi.nlm.nih.gov/pubmed/31844714 http://dx.doi.org/10.1016/j.heliyon.2019.e02780 |
work_keys_str_mv | AT alrefaeesalhahhamed methodsforthereactionofalkeneswithactivatedtungsticacid AT apblettallenw methodsforthereactionofalkeneswithactivatedtungsticacid |