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Crystal structure and Hirshfeld surface analysis of a zinc xanthate complex containing the 2,2′-bipyridine ligand
In the title compound, (2,2′-bipyridine-κ(2) N,N′)bis(2-methoxyethyl xanthato-κS)zinc(II), [Zn(C(4)H(7)O(2)S(2))(2)(C(10)H(8)N(2))], the Zn(II) ion is coordinated to two N atoms of the 2,2′-bipyridine ligand and two S atoms from two 2-methoxyethyl xanthate ligands. The Zn(II) ion lies on a cr...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895936/ https://www.ncbi.nlm.nih.gov/pubmed/31871745 http://dx.doi.org/10.1107/S2056989019014968 |
Sumario: | In the title compound, (2,2′-bipyridine-κ(2) N,N′)bis(2-methoxyethyl xanthato-κS)zinc(II), [Zn(C(4)H(7)O(2)S(2))(2)(C(10)H(8)N(2))], the Zn(II) ion is coordinated to two N atoms of the 2,2′-bipyridine ligand and two S atoms from two 2-methoxyethyl xanthate ligands. The Zn(II) ion lies on a crystallographic twofold rotation axis and has distorted tetrahedral coordination geometry. In the crystal, molecules are linked by weak C—H⋯O hydrogen bonds, forming supramolecular chains propagating along the a-axis direction. Weak intramolecular C—H⋯S hydrogen bonds are also observed. The intermolecular contacts in the crystal were further analysed using Hirshfield surface analysis, which indicates that the most significant contacts are H⋯H (36.3%), followed by S⋯H/H⋯S (24.7%), C⋯H/H⋯C (15.1%), O⋯H/H⋯O (14.4%), N⋯H/H⋯N (4.1%) and C⋯C (2.9%). |
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