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Crystal structure and Hirshfeld surface analysis of a zinc xanthate complex containing the 2,2′-bi­pyridine ligand

In the title compound, (2,2′-bi­pyridine-κ(2) N,N′)bis­(2-meth­oxy­ethyl xanthato-κS)zinc(II), [Zn(C(4)H(7)O(2)S(2))(2)(C(10)H(8)N(2))], the Zn(II) ion is coordinated to two N atoms of the 2,2′-bi­pyridine ligand and two S atoms from two 2-meth­oxy­ethyl xanthate ligands. The Zn(II) ion lies on a cr...

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Detalles Bibliográficos
Autores principales: Qadir, Adnan M., Kansiz, Sevgi, Rosair, Georgina M., Dege, Necmi, Safyanova, Inna S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895936/
https://www.ncbi.nlm.nih.gov/pubmed/31871745
http://dx.doi.org/10.1107/S2056989019014968
Descripción
Sumario:In the title compound, (2,2′-bi­pyridine-κ(2) N,N′)bis­(2-meth­oxy­ethyl xanthato-κS)zinc(II), [Zn(C(4)H(7)O(2)S(2))(2)(C(10)H(8)N(2))], the Zn(II) ion is coordinated to two N atoms of the 2,2′-bi­pyridine ligand and two S atoms from two 2-meth­oxy­ethyl xanthate ligands. The Zn(II) ion lies on a crystallographic twofold rotation axis and has distorted tetra­hedral coordination geometry. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds, forming supramolecular chains propagating along the a-axis direction. Weak intra­molecular C—H⋯S hydrogen bonds are also observed. The inter­molecular contacts in the crystal were further analysed using Hirshfield surface analysis, which indicates that the most significant contacts are H⋯H (36.3%), followed by S⋯H/H⋯S (24.7%), C⋯H/H⋯C (15.1%), O⋯H/H⋯O (14.4%), N⋯H/H⋯N (4.1%) and C⋯C (2.9%).