An iridium complex with an unsupported Ir—Zn bond: di­iodido­(η(5)-penta­methyl­cyclo­penta­dien­yl)bis­(tri­methyl­phosphane)iridiumzinc(Ir—Zn) benzene hemisolvate

The title compound, [IrZnI(2)(C(10)H(15))(C(3)H(9)P)(2)]·0.5C(6)H(6) or [Cp*(PMe(3))(2)Ir]-[ZnI(2)] (Cp* = cyclo-C(5)Me(5)) was obtained and characterized as its benzene solvate [Cp*(PMe(3))(2)Ir]-[ZnI(2)]·0.5C(6)H(6). The bimetallic complex in this structure contains the Lewis-acidic fragment ZnI(2...

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Autores principales: Taullaj, Fioralba, Lough, Alan J., Fekl, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895938/
https://www.ncbi.nlm.nih.gov/pubmed/31871738
http://dx.doi.org/10.1107/S2056989019014622
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author Taullaj, Fioralba
Lough, Alan J.
Fekl, Ulrich
author_facet Taullaj, Fioralba
Lough, Alan J.
Fekl, Ulrich
author_sort Taullaj, Fioralba
collection PubMed
description The title compound, [IrZnI(2)(C(10)H(15))(C(3)H(9)P)(2)]·0.5C(6)H(6) or [Cp*(PMe(3))(2)Ir]-[ZnI(2)] (Cp* = cyclo-C(5)Me(5)) was obtained and characterized as its benzene solvate [Cp*(PMe(3))(2)Ir]-[ZnI(2)]·0.5C(6)H(6). The bimetallic complex in this structure contains the Lewis-acidic fragment ZnI(2) bonded to the Lewis-basic fragment Cp*(PMe(3))(2)Ir, with an Ir—Zn bond distance of 2.452 (1) Å. The compound was obtained by reacting [Cp*(PMe(3))IrI(2)] with 2-Ad(2)Zn (2-Ad = 2-adamant­yl), resulting in the reduction of the Ir(III) complex and formation of the Ir(I)–Zn(II) adduct. The crystal studied was a twin by non-merohedry with a refined BASF parameter of 0.223 (1).
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spelling pubmed-68959382019-12-23 An iridium complex with an unsupported Ir—Zn bond: di­iodido­(η(5)-penta­methyl­cyclo­penta­dien­yl)bis­(tri­methyl­phosphane)iridiumzinc(Ir—Zn) benzene hemisolvate Taullaj, Fioralba Lough, Alan J. Fekl, Ulrich Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [IrZnI(2)(C(10)H(15))(C(3)H(9)P)(2)]·0.5C(6)H(6) or [Cp*(PMe(3))(2)Ir]-[ZnI(2)] (Cp* = cyclo-C(5)Me(5)) was obtained and characterized as its benzene solvate [Cp*(PMe(3))(2)Ir]-[ZnI(2)]·0.5C(6)H(6). The bimetallic complex in this structure contains the Lewis-acidic fragment ZnI(2) bonded to the Lewis-basic fragment Cp*(PMe(3))(2)Ir, with an Ir—Zn bond distance of 2.452 (1) Å. The compound was obtained by reacting [Cp*(PMe(3))IrI(2)] with 2-Ad(2)Zn (2-Ad = 2-adamant­yl), resulting in the reduction of the Ir(III) complex and formation of the Ir(I)–Zn(II) adduct. The crystal studied was a twin by non-merohedry with a refined BASF parameter of 0.223 (1). International Union of Crystallography 2019-11-05 /pmc/articles/PMC6895938/ /pubmed/31871738 http://dx.doi.org/10.1107/S2056989019014622 Text en © Taullaj et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Taullaj, Fioralba
Lough, Alan J.
Fekl, Ulrich
An iridium complex with an unsupported Ir—Zn bond: di­iodido­(η(5)-penta­methyl­cyclo­penta­dien­yl)bis­(tri­methyl­phosphane)iridiumzinc(Ir—Zn) benzene hemisolvate
title An iridium complex with an unsupported Ir—Zn bond: di­iodido­(η(5)-penta­methyl­cyclo­penta­dien­yl)bis­(tri­methyl­phosphane)iridiumzinc(Ir—Zn) benzene hemisolvate
title_full An iridium complex with an unsupported Ir—Zn bond: di­iodido­(η(5)-penta­methyl­cyclo­penta­dien­yl)bis­(tri­methyl­phosphane)iridiumzinc(Ir—Zn) benzene hemisolvate
title_fullStr An iridium complex with an unsupported Ir—Zn bond: di­iodido­(η(5)-penta­methyl­cyclo­penta­dien­yl)bis­(tri­methyl­phosphane)iridiumzinc(Ir—Zn) benzene hemisolvate
title_full_unstemmed An iridium complex with an unsupported Ir—Zn bond: di­iodido­(η(5)-penta­methyl­cyclo­penta­dien­yl)bis­(tri­methyl­phosphane)iridiumzinc(Ir—Zn) benzene hemisolvate
title_short An iridium complex with an unsupported Ir—Zn bond: di­iodido­(η(5)-penta­methyl­cyclo­penta­dien­yl)bis­(tri­methyl­phosphane)iridiumzinc(Ir—Zn) benzene hemisolvate
title_sort iridium complex with an unsupported ir—zn bond: di­iodido­(η(5)-penta­methyl­cyclo­penta­dien­yl)bis­(tri­methyl­phosphane)iridiumzinc(ir—zn) benzene hemisolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895938/
https://www.ncbi.nlm.nih.gov/pubmed/31871738
http://dx.doi.org/10.1107/S2056989019014622
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